Electron-Poor Iridium Pincer Complexes as Dehydrogenation Catalysts : Investigations into Deactivation through Formation of N2, CO, and Hydride Complexes
A range of derivatives of an iridium pincer complex with a bis-trifluoromethyl-substituted ligand have been studied to determine how their properties differ from those of similar systems. The emphasis is on derivatives valuable for catalytic acceptorless dehydrogenation, including intermediates and deactivation products. The studies highlight small but important differences in the electron richnes