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Comparison of the chemical properties of iron and cobalt porphyrins and corrins.

Density functional calculations have been used to compare various geometric, electronic and functional properties of iron and cobalt porphyrin (Por) and corrin (Cor) species. The investigation is focussed on octahedral MII/III complexes (where M is the metal) with two axial imidazole ligands (as a model of b and c type cytochromes) or with one imidazole and one methyl ligand (as a model of methylc

The diffusion of water vapour through pulp and paper

The diffusion of water vapour through pulp and paper was investigated experimentally in a diffusion cell. The diffusion cell consisted of two chambers differing in relative humidity. Any given sample was placed as a barrier between the two chambers. Two pulp qualities and eleven paper grades were included in the investigation. The diffusivities measured ranged from 2.1-10(-8) m2/s to 5.4.10(-6) m2

Molecularly imprinted polymers in capillary electrochromatography: Recent developments and future trends.

The developments in molecularly imprinted polymer (MIP)-based capillary electrochromatography (CEC) achieved during the past years are reviewed in this article. The MIP is prepared using a templated polymerization reaction and results in a material with a high selectivity towards a predetermined target. The selectivity of the MIP is comparable to that of the biological antibodies, however, the MIP

Thin layers of GaInP, GaP and GaAsP in metalorganic vapour phase epitaxy-grown resonant tunnelling diodes

We have studied the epitaxial growth and electrical performance of Al-free, GaAs-based, resonant tunnelling diodes (RTDs) including thin barriers of GaInP, GO, or GaAsxP1-x. n-Type tunnelling diodes have been fabricated and the symmetry in the current-voltage (I-V) characteristics, as well as the peak-to-valley ratios, are found to be sensitive probes for the inter-face quality in the heterostruct

Response criteria for rheumatoid arthritis in clinical practice - how useful are they?

Objective: To compare the performance of the American College of Rheumatology (ACR), European League Against Rheumatism (EULAR), and simple disease activity index (SDAI) response criteria for rheumatoid arthritis at the individual level in an observational cohort. Methods: 184 outpatients were followed using a structured protocol. For each patient, the responses according to ACR 20% and 50%, EULAR

Parental participation in the care of hospitalized children

The purpose of this study was to investigate those parts of the care of hospitalized children that their parents perform, the nursing tasks the parents themselves felt they could manage and whether parents' and staff members' opinions coincided. A questionnaire was given to parents of children between one week and five years of age who were hospitalized at a pediatric surgical department during a

Acupuncture mechanisms for clinical long-term effects, a hypothesis

In our clinical research, we have drawn the conclusion that meaningful long-term (> 6 months) pain relieving effects can be seen in a proportion of patients suffering from nociceptive pain. What are the mechanisms behind this? From the existing experimental data, some important conclusions can be drawn: A significant proportion of the animal research only represents short-term hypoalgesia probably

Sensory nerve inactivation by resiniferatoxin improves insulin sensitivity in male obese Zucker rats

Recent studies have suggested that sensory nerves may influence insulin secretion and action. The present study investigated the effects of resiniferatoxin (RTX) inactivation of sensory nerves ( desensitization) on oral glucose tolerance, insulin secretion and whole body insulin sensitivity in the glucose intolerant, hyperinsulinemic, and insulin-resistant obese Zucker rat. After RTX treatment (0.

Från Koranen till Ben Hur - Gunnar Jarrings samling av östturkiska handskrifter

In 1982, the Swedish diplomat and Turkologist Gunnar Jarring (1907–2002) donated his unique collection of Eastern Turkestan manuscripts to the Lund University Library. The Jarring Collection at Lund is the third biggest collection of Eastern Turkic manuscripts in the world and consists of 560 pieces, many of which are miscellanies. It is a broad collection and represents the history and culture of

Magnetotransport properties of short period GaMnAs/InGaAs superlattices

Magnetotransport properties of GaMnAs/InGaAs superlattice structure and GaMnAs/GaAs single layers have been investigated from 4 to 300 K and magnetic fields up to 22.5 T. All these magnetic semiconductors show the so-called "paramagnetic-to-ferromagnetic phase transition''. However, in GaMnAs/InGaAs superlattice beside the Curie Wiess temperature (T-c similar to 40 K), a new phase transition is ob

Coalescence times and the Meselson effect in asexual eukaryotes

In asexual eukaryotes, the two allelic gene copies at a locus are expected to become highly divergent as a result of the independent accumulation of mutations in the absence of segregation. If sexual reproduction was abandoned millions of generations ago, intra-individual allelic divergences can be significantly larger than in species that reproduce sexually. Owing to the disputed existence of tru

District Heating Substations. Performance, Operation and Design.

This thesis work is concerned with the efficient layout and operation of substations, i.e. those district heating (DH) system units which connect the network and internal building heating systems, such as radiator heating systems and domestic hot water distribution networks. The ambition was to make realistic investigations closely related to practical technologies within the field. The themes of