Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier

The cryptomonads is a well-defined lineage of unicellular eukaryotes, composed of several marine and freshwater groups. However, the evolutionary relationships among these groups are unclear due to conflicting inferences between morphological and molecular phylogenies. Here, we have inferred the evolutionary relationships among marine and freshwater species in order to better understand the import

We report on an experimental and theoretical investigation of x-ray absorption and resonant Auger electron spectra of gas phase O(2) recorded in the vicinity of the O 1s-->sigma(*) excitation region. Our investigation shows that core excitation takes place in a region with multiple crossings of potential energy curves of the excited states. We find a complete breakdown of the diabatic picture for

Abstract in German Die Bestimmung des prostataspezifischen Antigens (PSA) ist in der Frühdiagnostik des Prostatakarzinoms nach wie vor von zentraler Bedeutung. Ein ungelöstes Problem ist jedoch die geringe Spezifität dieses organ- aber nicht karzinomspezifischen Serummarkers, die bei einer hohen Anzahl von Patienten zu weiterer, dann invasiver Diagnostik führt, ohne dass ein Prostatakarzinom gefunDetection of prostate-specific antigen remains the mainstay in the early detection of prostate cancer. A problem yet unsolved is the lack of specificity of this organ- but not cancer-specific marker, which generates subsequent, invasive procedures in a high number of patients without detecting prostate cancer. While the separate detection of free PSA and the ratio of free to total PSA has signific

Interaction forces between charged interfaces in the presence of oppositely charged dendrimers are studied by experiment and simulation. The experiments involve direct force measurements with all atomic force microscope (AFM) between two negatively charged colloidal particles in the presence of adsorbed, positively charged globular dendrimers. The simulations are carried out by treating the macroi

Residual stress and distortion continue to be important issues in shipbuilding and are still subject to large amounts of research. This paper demonstrates how the type of welding process influences the amount of distortion. Many shipyards currently use submerged arc welding (SAW) as their welding process of choice. In this manuscript, the authors compare welds made by SAW with DC gas metal arc wel

The task of a fast correlation attack is to efficiently restore the initial content of a linear feedback shift register in a stream cipher using a detected correlation with the output sequence. We show that by modeling this problem as the problem of learning a binary linear multivariate polynomial, algorithms for polynomial reconstruction with queries can be modified through some general technique

Shallow marine, nearshore strata of earliest Campanian (Gonioteuthis granulataquadrata belemnite Zone) and latest Early Campanian (informal Belemnellocamax mammillatus belemnite zone) age in the Kristianstad Basin, southern Sweden, have yielded isolated leptoceratopsid teeth and vertebrae, representing the first record of horned dinosaurs from Europe. The new leptoceratopsid occurrence may support

Dampness in buildings has been linked to adverse health effects, but the specific causative agents are unknown. Mycotoxins are secondary metabolites produced by molds and toxic to higher vertebrates. In this study, mass spectrometry was used to demonstrate the presence of mycotoxins predominantly produced by Aspergillus spp. and Stachybotrys spp. in buildings with either ongoing dampness or a hist

In this paper, a novel data scaling method for pipelined FFT processors is proposed. By using data scaling, the FFT processor can operate on a wide range of input signals without performance loss. Compared to existing block scaling methods, like implementations of Convergent Block Floating Point (CBFP), the memory requirements can be reduced while preserving the SNR. The FFT processor has been syn

Water-soluble poly(acrylic acid) has been covalently labeled with a fluorescent hydrophobic chromophore, naphthalene (Np), randomly attached onto the polymer backbone with an amount of 3 mol %. The polymer, which is a new type of hydrophobically modified polymer denoted PAAMeNp-34, was investigated using steady-state fluorescence spectroscopy in aqueous solutions of different pH and in methanol. T

Current-voltage curves of molecular single-electron tunneling transistors are simulated based on a modified theory of single electronics that accounts for the discreteness of the energy spectrum of the molecule. The simulation was performed including effects of energy relaxation of the electrons in the molecule for two limiting cases of fast and slow relaxation, and for both equidistant and random

The lifetime broadening and molecular field splitting of the sodium dimer 2p core level is studied by x-ray photoelectron spectroscopy and by Auger electron spectroscopy. The lifetime of the Na 2p core hole has been determined to be 15 +/- 8 fs, much shorter than what has previously been reported for solid sodium. The molecular field splitting of this core level has been determined to be 42 +/- 10

BACKGROUND: The plasma level of endothelin-1 is locally increased during cooling but the net vasoconstrictor effect will be dependent on temperature effects on the vascular smooth muscle reactivity in response to the polypeptide. The aim of this study was to investigate the effect of cooling on the vascular smooth muscle response to endothelin-1 in human and rat veins. METHODS: Registration of vas

Mechanistic evidence linking chromosomal aberration (CA) to early stages of cancer has been recently supported by the results of epidemiological studies that associated CA frequency in peripheral lymphocytes of healthy individuals to future cancer incidence. To overcome the limitations of single studies and to evaluate the strength of this association, a pooled analysis was carried out. The pooled