Structure and stability of γ1-AuZn2.1 : A γ-brass-related complex phase in the Au-Zn System
γ1-AuZn2.1 in the Au-Zn binary system has been synthesized and its structure analyzed by single-crystal X-ray diffraction. It crystallizes in the trigonal space group P31m (No. 157) with ∼227 atoms per unit cell and represents a 3a × 3a × c superstructure of rhombohedrally distorted γ-Au5-x Zn8+y. The structure is largely tetrahedrally closed packed. The formation of γ1-AuZn2.1 can be understood w