Heterogeneous catalysts for selective oxidation of C-H bonds were synthesized by co-polymerization of new N-heterocyclic carbene-palladium(II) (NHC-PdII) monomers with divinylbenzene. The polymer-supported NHC-PdII-catalysed undirected C-H acetoxylation of simple and methylated arenes as well as polyarenes, with similar or superior efficiency compared to their homogeneous analogues. In particular,

The tracking performance parameters of the ATLAS Transition Radiation Tracker (TRT) as part of the ATLAS inner detector are described in this paper for different data-taking conditions in proton-proton, proton-lead and lead-lead collisions at the Large Hadron Collider (LHC). The performance is studied using data collected during the first period of LHC operation (Run 1) and is compared with Monte

Measurements of anisotropic flow Fourier coefficients (vn) for inclusive charged particles and identified hadrons π±, K±, p, and p produced at midrapidity in Cu+Au collisions at sNN=200 GeV are presented. The data were collected in 2012 by the PHENIX experiment at the Relativistic Heavy-Ion Collider (RHIC). The particle azimuthal distributions with respect to different-order symmetry planes Ψn, fo

In order to describe partially premixed supersonic combustion numerically, G/Z flamelet model is developed and compared with finite rate model in hybrid RANS/LES simulation to study the strut-injection supersonic combustion flow field designed by the German Aerospace Center. A new temperature calculation method based on time-splitting method of total energy is introduced in G/Z flamelet model. Sim

Protein identification through peptide mass mapping by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) has become a standard technique, used in many laboratories around the world. The traditional methodology often includes long incubations (6-24 h) and extensive manual steps. In an effort to address this, an integrated microanalytical platform has been d

A flow immunodetection system with high sample throughput capacity is described for the screening of various analytes. The immunochemical detection principle is based on the chromatographic separation of the formed immunocomplex (AbAg or AbAg*) and the free antigen (Ag) by a restricted access (RA) column, utilising size-exclusion and reversed-phase mechanism. A fluorescein labelled analyte (Ag*) w

The need for developing highly efficient solar cell devices have never been so pressing until recently when the urgency of using renewable energy sources becomes more evident. There are several promising technologies being explored by many groups with the sole purpose of optimizing harvesting sunlight and converting it to useful electricity. These include, but not limited to, dye- and quantum dot-

This thesis investigates the electronic properties of a number of novel III-V materials and material combinations for transistor applications. In particular, high-κ/InAs metal-oxide-semiconductor (MOS) structures and transport properties of GaSb nanowires have been studied. III-V semiconductors are potential candidates to replace Si-based electronics due to their outstanding electron transport pro

Bananas are widely consumed fruits with over 140 metric tons produced annually. As much as 336 metric tons of banana pseudo-stems, sheaths, piths, peels and leaves are produced annually. These wastes are usually discarded via composting, aerobic decomposition, incinerated or simply allowed to rot in the fields. However, these treatments may cause serious environmental and ecological problems. Mea

2-n-Heptyl4-hydroxyquinoline-N-oxide (HOQNO) inhibits the succinate:quinone oxidoreductase activity of isolated and membrane-bound succinate:menaquinone oxidoreductase of B. subtilis. The inhibition pattern resembles closely that observed for α-thenoyltrifluoroacetone and carboxins in the mitochondrial succinate:ubiquinone oxidoreductase: ca. 90% of the activity is highly sensitive to HOQNO (K i c

A feasibility study is presented and the achieved key design milestones towards the first application of Chemical Species Tomography by Near-IR Absorption Tomography on a heavy duty, large-bore marine engine to visualise relative mixture strength are described. The engine is equipped with pre-chamber ignition and operates using Liquefied Natural Gas with >88.9% methane content. Operation of the en

Direct conversion receivers are widely used for full duplex mobile radio communication systems. This paper describes a novel SAW-less single-ended RF amplifier connected to a single-ended mixer with a feedback loop that suppresses the second-order distortion from TX cross modulation of the LO-leakage as well as DC-offset at the mixer output. In Monte Carlo simulations the design achieves +47 dBm m

Parkinson's disease (PD) is a neurodegenerative disease where the degeneration of the nigrostriatal pathway leads to specific motor deficits. There is an unmet medical need for regenerative treatments that stop or reverse disease progression. Several growth factors have been investigated in clinical trials to restore the dopaminergic nigrostriatal pathway damaged in PD. Platelet-derived growth fac

Starch is a major energy source for all domains of life. Recent advances in structures of starch-degrading enzymes encompass the substrate complex of starch debranching enzyme, the function of surface binding sites in plant isoamylase, details on individual steps in the mechanism of plant disproportionating enzyme and a self-stabilised conformation of amylose accommodated in the active site of pla