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Highly Asymmetrical Porphyrins with Enhanced Push-Pull Character for Dye-Sensitized Solar Cells

A porphyrin -system has been modulated by enhancing the push-pull character with highly asymmetrical substitution for dye-sensitized solar cells for the first time. Namely, both two diarylamino moieties as a strong electron-donating group and one carboxyphenylethynyl moiety as a strong electron-withdrawing, anchoring group were introduced into the meso-positions of the porphyrin core in a lower sy

Magnetostratigraphic importance of secondary chemical remanent magnetizations carried by greigite (Fe3S4) in Miocene sediments, New Jersey shelf (IODP Expedition 313)

Paleomagnetic and mineral magnetic analyses were carried out on Miocene clays from upper unit II at Sites M0027 and M0028 recovered during Integrated Ocean Drilling Program Expedition 313 on the New Jersey shallow shelf. A zone of mixed polarity in the lower section of Hole M0028A and dual overlapping magnetization components in upper Hole M0027A indicate that the sediments may have been chemicall

New picture of jet quenching dictated by color coherence

We propose a new description of the jet quenching phenomenon observed in nuclear collisions at high energies in which coherent parton branching plays a central role. This picture is based on the appearance of a dynamically generated scale, the jet resolution scale, which controls the transverse resolution power of the medium to simultaneously propagating color probes. Since from the point of view

High serum adiponectin is associated with low blood haemoglobin in elderly men: the Swedish MrOS study

Objectives: Blood haemoglobin (Hb) concentration declines in elderly men, whilst the level of the adipocyte-derived protein adiponectin increases with age. The association between erythropoiesis and adiponectin in elderly men is unclear. The aim of this study was to determine whether adipokines such as adiponectin and leptin are associated with anaemia and Hb concentration in elderly community-dwe

Feasibility Study of Ubiquitous Interaction Concepts

There are all sorts of consumer electronics in a home environment. Using ”apps” to interact with each device is neither feasible nor practical in an ubicomp future. Prototyping and evaluating interaction concepts for this future is a challenge. This paper proposes four concepts for device discovery and device interaction implemented in a virtual environment. The interaction concepts were compared

High-resolution X-ray emission spectroscopy with transition-edge sensors: present performance and future potential.

X-ray emission spectroscopy (XES) is a powerful element-selective tool to analyze the oxidation states of atoms in complex compounds, determine their electronic configuration, and identify unknown compounds in challenging environments. Until now the low efficiency of wavelength-dispersive X-ray spectrometer technology has limited the use of XES, especially in combination with weaker laboratory X-r

Genome-Wide Association Identifies Nine Common Variants Associated With Fasting Proinsulin Levels and Provides New Insights Into the Pathophysiology of Type 2 Diabetes

OBJECTIVE-Proinsulin is a precursor of mature insulin and C-peptide. Higher circulating proinsulin levels are associated with impaired beta-cell function, raised glucose levels, insulin resistance, and type 2 diabetes (T2D). Studies of the insulin processing pathway could provide new insights about T2D pathophysiology. RESEARCH DESIGN AND METHODS-We have conducted a meta-analysis of genome-wide as

Oncogenic Pathways and Molecular Prognostics in Neuroblastoma

Neuroblastoma is an embryonal malignancy that accounts for 15% of all cancer related deaths amongst children. Although the overall survival of patients has been improving over the last decades, the high-risk neuroblastoma patients have a survival rate of

The Most Delicate Subject : A History of Sex Education Films in Sweden

The aim of this dissertation is to present a history of sex education films in Sweden, from their beginnings until the late 1970s, relating the films to the changing historical context of the Swedish welfare society. Within this framework, the dissertation explores two main sets of questions. First, utilizing a contextual understanding of genre, the dissertation analyzes how the films were produce

HIV disease progression - Impact of HIV-1 intersubtype recombination and association with HIV-2 evolution

Human immunodeficiency virus type 1 (HIV-1) and type 2 (HIV-2) are both causative agents of AIDS, with similar pathogenic characteristics. However, the rate of disease progression is highly variable both within and between HIV-1 and HIV 2, but the mechanisms involved in modulating the rate of disease progression remain poorly understood. Host genetics account for some of the variation within each

Molecular design of specific metal-binding peptide sequences from protein fragments: Theory and experiment

A novel strategy is presented for designing peptides with specific metal-ion chelation sites, based on linking computationally predicted ion-specific combinations of amino acid side chains coordinated at the vertices of the desired coordination polyhedron into a single polypeptide chain. With this aim, a series of computer programs have been written that 1) creates a structural combinatorial libra

Local Refinement for Stereo Regularization

Stereo matching is an inherently difficult problem due to ambiguous and noisy texture. The non-convexity and non- differentiability makes local linear (or quadratic) approximations poor, thereby preventing the use of standard local descent methods. Therefore recent methods are predominantly based on discretization and/or random sampling of some class of approximating surfaces (e.g. planes). While

Variation in Artemisia pollen seasons in Central and Eastern Europe

This paper aims to address some gaps in current knowledge by studying temporal and spatial variations in Artemisia pollen counts (2000-2009) at 13 sites located in different biogeographical areas of Central and Eastern Europe. Analysis showed that start dates of Artemisia pollen seasons are greatly dependent on temperature during June and July, with hot summer temperatures having a tendency to del

Structural and biochemical characterization of two heme binding sites on α1-microglobulin using site directed mutagenesis and molecular simulation.

α1-Microglobulin (A1M) is a reductase and radical scavenger involved in physiological protection against oxidative damage. These functions were previously shown to be dependent upon cysteinyl-, C34, and lysyl side-chains, K(92, 118,130). A1M binds heme and the crystal structure suggests that C34 and H123 participate in a heme binding site. We have investigated the involvement of these five residue

Monitoring spatiotemporal variation in abundance and dispersal by a pheromone-kairomone system in the threatened saproxylic beetles Osmoderma eremita and Elater ferrugineus

Pheromone monitoring could provide unique spatial and temporal information about rare and threatened insect species for conservation purposes. Pheromone traps may be especially valuable in detecting fluctuations and declines in vulnerable species, if trap catch can be related to population density. We exploited the pheromone-kairomone system of the hermit beetle Osmoderma eremita and its predator,

Surgical management of Dupuytren's contracture in Europe: regional analysis of a surgeon survey and patient chart review

Aim We explored regional variations in the surgical management of patients with Dupuytren's contracture (DC) in 12 European countries using a surgeon survey and patient chart review. Methods Twelve countries participated: Denmark, Finland, Sweden (Nordic region); Czech Republic, Hungary, Poland (East); France, Germany, the Netherlands, UK (West); Italy, Spain (Mediterranean). For the survey, a ran

New shape minimum in Yb-160: Evidence for a triaxial, strongly deformed band

A high-spin rotational band was observed in the N=90 nucleus Yb-160 with moment of inertia and decay characteristics very similar to recently discovered sequences in Er-157,Er-158. These latter structures were discussed in terms of strongly deformed triaxial bands. Detailed cranked Nilsson-Strutinsky calculations were performed that predict that well-deformed triaxial structures are also expected