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Endoglucanase sensitivity for substituents in methyl cellulose hydrolysis studied using MALDI-TOFMS for oligosaccharide analysis and structural analysis of enzyme active sites

The properties of modified cellulose polymers, such as methylcellulose, are significantly influenced by the distribution of substituents along the polymer backbone. This distribution is difficult to determine due to the lack of suitable analytical methods. One approach is to use cellulose-degrading enzymes to gain information from the capability of the enzymes to cleave the bonds between glucose u

Spectral tuning in biology

Spectral tuning is a diverse topic, both with regard to mechanism and with regard to biological significance. We have touched upon a related topic already when dealing with quantum dots in Chapter 5. In organisms, spectral tuning can be achieved both by chemical means (choice of pigment) and by physical means. The latter aspect is treated towards the end of the chapter in a section on structural c

Channel estimation with superimposed pilot sequence

For the purpose of various synchronization tasks (including carrier phase, time, frequency, and frame synchronization), one may add a known pilot sequence, typically a pseudo-noise sequence, to the unknown data sequence. This approach is known as a spread-spectrum pilot technique or as a superimposed pilot sequence technique. In this paper, we apply the superimposed pilot sequence technique for th

The amateur scientist's spectrophotometer

This chapter describes the construction and performance of a spectrophotometer that is very easily constructed from a DVD, a digital camera, a lamp and some cardboard, wood, and sheet metal.

Coupling elements for substructure modelling of lightweight multi-storey buildings

Abstract in UndeterminedAccurately modelling the dynamic behaviour of multi-storey buildings in wood requires the geometry involved to be represented in great detail, resulting in systems having many millions of degrees of freedom. Consequently, there is a need for model order reduction and the methodology of substructure modelling is employed here to create reduced models for analysis of low-freq

Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands : a case of dual emission revisited

Iron N-heterocyclic carbene (FeNHC) complexes with long-lived charge transfer states are emerging as a promising class of photoactive materials. We have synthesized [FeII(ImP)2] (ImP = bis(2,6-bis(3-methylimidazol-2-ylidene-1-yl)phenylene)) that combines carbene ligands with cyclometalation for additionally improved ligand field strength. The 9 ps lifetime of its 3MLCT (metal-to-ligand charge tran

Association of Somatic TET2 Mutations With Giant Cell Arteritis

Objective: Giant cell arteritis (GCA) is an age-related vasculitis. Prior studies have identified an association between GCA and hematologic malignancies (HMs). How the presence of somatic mutations that drive the development of HMs, or clonal hematopoiesis (CH), may influence clinical outcomes in GCA is not well understood. Methods: To examine an association between CH and GCA, we analyzed sequen

Development and demonstration of 2D-LIF for studies of mixture preparation in SI engines

Laser-induced fluorescence (LIF) has been developed for visualization of fuel distribution fields in an operating spark-ignition (SI) engine. Since the standard research fuel iso-octane, does not yield a useful LIF signal a fluorescent additive was used. None of the commonly used seeds were found adequate. A seed not commonly used in this context, 3-pentanone, C2H5COC2H5, was chosen due to favorab

Costs and quality of life of patients with multiple sclerosis in Europe

Objective: To assess overall resource consumption, work capacity and quality of life of patients with multiple sclerosis in nine European countries. Methods: Information on resource consumption related to multiple sclerosis, informal care by relatives, productivity losses and overall quality of life (utility) was collected with a standardised pre-tested questionnaire from 13186 patients enrolled i

Intracerebral microdialysis in clinical practice: baseline values for chemical markers during wakefulness, anesthesia, and neurosurgery

OBJECTIVE: The study was undertaken to measure baseline values for chemical markers in human subjects during wakefulness, anesthesia, and neurosurgery, using intracerebral microdialysis. METHODS: Microdialysis catheters were inserted into normal posterior frontal cerebral cortex in nine patients who were undergoing surgery to treat benign lesions of the posterior fossa. The perfusion rate was 1.0

The Weakest Link Human Behaviour and the Corruption of Information Security Management in Organisations - an Analytical Framework

In this paper we introduce the norm-injection analysis framework, a construct which can be employed to aid analysis of processes that affect information security management (ISM) in organisations. The underpinnings of this framework draw on and evolve - theories about how apparently mundane organisational processes, particularly managerial demands on employees, may in some instances lead to undesi

Turbo codes: Correlated extrinsic information and its impact on iterative decoding performance

The performance of a turbo code is dependent on two properties of the code: its distance spectrum and its suitability to be iteratively decoded. The performance of iterative decoding depends on the quality of the extrinsic inputs; badly correlated extrinsic inputs can deteriorate the performance. While most turbo coding literature assumes that the extrinsic information is uncorrelated, we investig