[FeFe]-hydrogenase from green algae (HydA1) is the most efficient hydrogen (H2) producing enzyme in nature and of prime interest for (bio)technology. Its active site is a unique six-iron center (H-cluster) composed of a cubane cluster, [4Fe4S]H, cysteine-linked to a diiron unit, [2Fe]H, which carries unusual carbon monoxide (CO) and cyanide ligands and a bridging azadithiolate group. We have probe

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This article concerns small state security from a cognitive perspective and investigates Estonia as a security actor as perceived by all littoral Baltic Sea states. Drawing on unique elite survey and interview data, the article unpacks similarities and differences among internal (Estonian) and external perceptions of security, threats, and capabilities. The investigation is theoretically informed

Minusräntan har förvärrat de finansiella obalanserna, sänkt värdet på den svenska kronan och bidragit till ökade förmögenhetsklyftor. Det skriver nationalekonomerna Fredrik N G Andersson och Lars Jonung.

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The class of [NiFe]-hydrogenases comprises oxygen-sensitive periplasmic (PH) and oxygen-tolerant membrane-bound (MBH) enzymes. For three PHs and four MBHs from six bacterial species, structural features of the nickel-iron active site of hydrogen turnover and of the iron-sulfur clusters functioning in electron transfer were determined using X-ray absorption spectroscopy (XAS). Fe-XAS indicated surp

High-resolution X-ray absorption spectroscopy with narrow-band X-ray emission detection, supported by density functional theory calculations (XAES-DFT), was used to study a model complex, ([Fe2(μ-adt)(CO) 4(PMe3)2] (1, adt = S-CH2-(NCH 2Ph)-CH2-S), of the [FeFe] hydrogenase active site. For 1 in powder material (1powder), in MeCN solution (1′), and in its three protonated states (1H, 1Hy, 1HHy; H

Detailed optical and EPR analyses of states induced in dark-adapted PS II membranes by cryogenic illumination permit characterization and quantification of all pigment derived donors and acceptors, as well as optically silent (in the visible, near infrared) species which are EPR active. Near complete turnover formation of QA- is seen in all centers, but with variable efficiency, depending on the d

This sophisticated book presents new theoretical and analytical insights into the momentous events in the Arab world that began in 2011 and, more importantly, into life and politics in the aftermath of these events. Focusing on the qualities of the sensory world, Maria Frederika Malmström explores the dramatic differences after the Egyptian revolution and their implications for society—the lack of

Trots att nordisk rätt i stor utsträckning präglas av en funktionalistiskt inställning så skiljer sig uppfattningen om hur frågeställningar inom den dynamiska sakrätten ska lösas länderna emellan. I artikeln åskådliggörs hur det svenska förhållningssättet präglas av lagstadgade regler, medan det i Danmark finns en mjukare och tämligen pragmatiskt attityd med utrymme för mer nyanserade lösningar. F

The sayings of the Desert Fathers had an important role in the monastic education and were very widespread. Originally written down in Greek, they were soon translated into all the main languages in the medieval Europe, and underwent transformations as they were copied. The sayings were organized in different ways, mainly alphabetically or according to themes, and as they were copied the repertoir

Ten square-based pyramidal molybdenum complexes with different sulfur donor ligands, that is, a variety of dithiolenes and sulfides, were prepared, which mimic coordination motifs of the molybdenum cofactors of molybdenum-dependent oxidoreductases. The model compounds were investigated by Mo K-edge X-ray absorption spectroscopy (XAS) and (with one exception) their molecular structures were analyze

The electrons extracted from the CaMn4 cluster during water oxidation in photosystem II are transferred to P680+ via the redox-active tyrosine D1-Tyr161 (YZ). Upon YZ oxidation a proton moves in a hydrogen bond toward D1-His190 (HisZ). The deprotonation and reprotonation mechanism of YZ-OH/Y Z-O is of key importance for the catalytic turnover of photosystem II. By light illumination at liquid heli

The redox-active tyrosine residue (YZ) plays a crucial role in the mechanism of the water oxidation. Metalloradical electron paramagnetic resonance (EPR) signals reflecting the light-induced YZ· in magnetic interaction with the CaMn4-cluster in the particular S-state, YZ·SX intermediates, have been found in intact photosystem II. These so-called split EPR signals are induced by illumination at cry

The interaction EPR split signals from photosystem II (PSII) have been reported from the S0, S1, and S3 states. The signals are induced by illumination at cryogenic temperatures and are proposed to reflect the magnetic interaction between YZ• and the Mn 4Ca cluster. We have investigated the formation spectra of these split EPR signals induced in PSII enriched membranes at 5 K using monochromatic l

City centre offerings, including shopping, restaurants and cafés, and a lively atmosphere are vital place attributes, which together with several other elements create an attractive place. However, city centre retailing is facing serious competition from e-commerce and external shopping malls, and dying city centres appear to have become a worldwide epidemic in the last decade. To retain visitors