Photophysics of an Intramolecular Hydrogen-Evolving Ru-Pd Photocatalyst
Photoinduced electron-transfer processes within a precatalyst for intramolecular hydrogen evolution [(tbbpy)(2)Ru(tpphz)PdCl2](2+) (RuPd; tbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine, tpphz = tetrapyrido[3,2-a:2',3'c:3 '',2 '',-h:2"',3'''-j]phenazine) have been studied by resonance Raman and ultrafast time-resolved absorption spectroscopy. By comparing the photophysics of the [(tbbpy)(2)Ru(tpphz)](2
