Synthesis of novel Fe(II)-complexes and study on their catalytic properties in asymmetric epoxidation
Two novel tetradentate ligands N, N’-Dimethyl-N, N’-bis(2-(chloromethyl)-1-methylbenzimidazole)- ethane-1,2-diamine (mepL), (-)-2-(((S)-2-((S)-1-(benzimidazol-2-ylmethyl) pyrrolidin-2-yl) pyrrolidin-1-yl)methyl)benzimidazole (PDPL) and their iron complexes [Fe(mepL)(CH3CN)2](SbF6)2 (SbF62), [Fe(CF3SO3)2(PDPL)] (OTf1) and [Fe(PDPL) (CH3CN)2](SbF6)2 (SbF61) were synthesized and characterized with IR