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Toward solar energy conversion into fuels: Design and synthesis of ruthenium-manganese supramolecular complexes to mimic the function of photosystem II

To mimic the electron donor side of Photosystem II (PSII), a number of supramolecular model complexes have been designed and synthesized. Ruthenium(II) tris-bipyridyl complexes have been used in most cases as photosensitizers, mimicking the function of P-680 in PSII. As electron donors, monomeric and dimeric manganese complexes and tyrosine have been introduced into the supramolecular systems, mod

Substitution reactions of [Pt(dien)Cl](+), [Pt(dien)(GSMe)](2+), cis-[PtCl2(NH3)(2)] and cis-[Pt(NH3)(2)(GSMe)(2)](2+) (GSMe = S-methylglutathione) with some sulfur-bonding chemoprotective agents

Sulfur-containing compounds are used as rescue agents to protect normal tissue from the toxic side effects of cis-[PtCl2(NH3)(2)] (cisplatin) without affecting its anti-tumour activity. Reactions of the model complexes [Pt(dien)Cl](+) (1) and [Pt(dien)(GSMe)](2+) (2) (GSMe = S-methylglutathione) with the rescue agents glutathione (GSH), thiourea, thiosulfate, and diethyldithiocarbamate (DDTC) have

Protein complexes of the plant plasma membrane resolved by Blue Native PAGE

With the characterization of the total genomes of Arabidopsis thaliana and Oryza sativa, several putative plasma membrane components have been identified. However, a lack of knowledge at the protein level, especially for hydrophobic proteins, have hampered analyses of physiological changes. To address whether protein complexes may be present in the native membrane, we subjected plasma membranes is

Deuteron production in e+e−-annihilation

We argue that ine + e –-annihilation (including -decay) deuteron production should be given by the overlap of the deuteron wave function with the wave function of apn-pair. The production rate depends sensitively upon the size of the production region. Taking into account the strong correlation between protons and neutrons, experimental results for -decay are consistent with the size expected in t

A new approach to the phase behavior of oppositely charged polymers and surfactants

The complex salt (ionic surfactant + polymeric counterion) cetyltrimethylammonium polyacrylate (CTAPA) has been synthesized, and its aqueous mixtures with cetyltrimethylammonium bromide (CTABr) have been studied. These mixtures differ from conventional oppositely charged polymer/surfactant mixtures in that the conventional counterion of the polyion (usually sodium, for the polyacrylate) is absent,

Plum-pudding gels as a platform for drug delivery: Understanding the effects of the different components on the diffusion behavior of solutes

The internal structure of composite gels made of responsive microgel particles inserted into a bulk hydrogel (N-isopropylacrylamide microgel particles in a cross-linked dimethylacrylamide matrix) has been investigated from the diffusion behavior of poly(ethylene glycol) (PEG) probes through the network, in the absence of specific interactions between the diffusing molecules and the system. The eff

Leukocyte rolling is exclusively mediated by P-selectinin colonic venules.

1. The objective of the present study was to examine the role of the endothelial selectins (i.e. P- and E-selectin) in leukocyte-endothelium interactions in colonic venules by use of intravital microscopy. 2. Balb/c mice were exposed to dextran sodium sulphate (DSS) in the drinking water for 5 days or treated intraperitoneally (i.p.) with tumour necrosis factor-alpha (TNF-alpha) for 3 h. 3. In DSS

Effects of selective beta 2 and beta 3-adrenoceptor agonists on detrusor hyperreflexia in conscious cerebral infarcted rats

Purpose: We evaluated the effects of beta-adrenoceptor agonists on detrusor hyperreflexia in cerebral infarcted rats. Materials and Methods: To produce cerebral infarction in Sprague-Dawley rats the left middle cerebral artery was occluded by introducing a monofilament nylon thread into the artery. In sham operated rats the same artery was exposed but not occluded. After these operations cystometr

Self-association of lysozyme as seen by magnetic relaxation dispersion

The pH and salt dependent self-association of hen egg-white lysozyme (HEWL) has been studied extensively, mainly by scattering techniques, but it has proven difficult to distinguish oligomerization from long-range interactions. Because HEWL is the principal model system in studies of protein crystallization, it is important to establish its oligomerization behavior unambiguously. Here, we address

X-linked Alport syndrome: Natural history and genotype-phenotype correlations in girls and women belonging to 195 families: A "European community Alport syndrome concerted action" study

Alport syndrome (AS) is a type IV collagen hereditary disease characterized by progressive hematuric nephritis, hearing loss, and ocular changes. Mutations in the COL4A5 collagen gene are responsible for the more common X-linked dominant form of the disease characterized by much less severe disease in girls and women. A "European Community Alport Syndrome Concerted Action" (ECASCA) group was estab

External costs of transports imposed on neighbours and fellow road users

Popular Abstract in Swedish Avhandlingen består av en introduktion samt fyra artiklar. Avhandlingen behandlar externa kostnader till följd av väg- och järnvägstransporter. Den första artikeln skattar sambandet mellan antalet vägtrafikolyckor och antalet fordon på vägen. Fordonsflödet behandlas dels som bestående av homogena fordon och dels som bestående av bilar och lastbilar. Resultatet tyder på This thesis consists of an introductory chapter and four research papers, summarized as follows. The overall purpose is to study various external effects of the transport system; effects that are not considered (or not fully considered) today. The first paper estimates the relationship between accident frequency and homogeneous and inhomogeneous traffic flows, which is useful for calculating the

Laser Diagnostics of HCCI and Partially Premixed Combustion

Popular Abstract in Swedish Undersökningarna som presenteras i avhandlingen behandlar mätning av produkter från och händelser i förbränningsprocessen genom att använda laserbaserade mätmetoder. Ett antal olika körfall, som HCCI och partially premixed combustion (PPC), har undersökts. I de första mätningarna som presenteras jämförs uppmätta flödesfält i cylindern med resultat från CFD och blåsriggThe work presented in this thesis deals with measuring in-cylinder combustion species and events using different laser-based diagnostic methods. A variety of engine operating modes, like HCCI and partially premixed diesel combustion, have been investigated. In the very first measurements, in-cylinder flow-fields were compared to CFD and steady-state blow rig results. After that, the ignition and

Comparison of clinical and physical measures of image quality in chest and pelvis computed radiography at different tube voltages

The aim of this work was to study the dependence of image quality in digital chest and pelvis radiography on tube voltage, and to explore correlations between clinical and physical measures of image quality. The effect on image quality of tube voltage in these two examinations was assessed using two methods. The first method relies on radiologists' observations of images of an anthropomorphic phan