Restrictions on the rate of absorption when evaluating sorption isotherms obtained using a micro-calorimetric technique
One interestingway of measuring sorption isotherms and heats of sorption is the newly developed micro-calorimetric method. It turns out, however, that the adsorption kinetics must be proven to be rapid enough to fulfill the assumptions behind the theory for the determination of the isotherm to be valid. Here, the lower limit of the accepted rate of adsorption will be analyzed by making calculation