Competition between weak OH·π and CH·O hydrogen bonds : THz spectroscopy of the C2H2 - H2O and C2H4 - H2O complexes
THz absorption spectra have been recorded for the weakly bound molecular complexes of H2O with C2H4 and C2H2 embedded in cryogenic neon matrices at 2.8 K. The observation and assignment of a large-amplitude acceptor OH librational mode of the C2H2 - H2O complex at 145.5 cm−1 confirms an intermolecular CH⋯O hydrogen-bonded configuration of C2v symmetry with the H2O subunit acting as the hydrogen bo