Titanium incorporation and Ti-VI(3+)-Ti-IV(4+) charge transfer in synthetic diopside
A series of Ti-doped diopside samples synthesized by fluxgrowth methods under reducing conditions were investigated by microanalytical methods and optical absorption spectroscopy, to assess Ti incorporation mechanisms, valence states, and related electronic transitions. Chemical characterization show that Ti occurs both in the tri-and tetravalent states, with Ti4+ preferentially ordered to the tet
