[W(N2O2)(HN2O2)] (H4N2O2 = N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine) with a noninnocent ligand was formed by reaction of the alkoxide precursor [W(eg)3] (eg = the 1,2-ethanediolate dianion) with two equivalents of ligand. The phenol groups on one of the ligands are completely deprotonated and the ligand coordinates in a tetradentate fashion, whereas the other ligand is trid

Background: Adverse health effects of particulate matter (PM) vary with chemical composition; however, evidence regarding which elements are the most detrimental is limited. The roof space area provides an open and stable environment for outdoor PM to settle and deposit. Therefore, this study used roof space PM samples as a proxy of residential cumulative exposure to outdoor air pollution to inves

Film cooling, as an effective protection technology, is widely applied in gas turbines to prevent components like vane blades from the hot mainstream. However, ash and other contaminants contained in the gas easily deposit on blade surfaces, which results in blockages inside the film holes and a reduction of the coverage area of the coolant air. Two blockage configurations (hemispherical and tetra

For district heating systems, prediction of the heat load is a very important topic for energy storage and optimized operation. For large and complex heating systems, most prediction models in previous publications only considered the influence of outdoor temperature, whereas the indoor temperature and thermal inertia of buildings were not included. For an energy-efficient residential building in

Abstract: Two new salicylaldiminato-copper(II) complexes, [Cu(L1)2] (1) and [Cu(L2)2] (2) (where HL1= 4 -tert-Butyl-2-[(thiophen-2-ylmethylimino)-methyl]-phenol and HL2= 2 , 4 -Di-tert-butyl-6-[(thiophen-2-ylmethylimino)-methyl]-phenol), endowed with a pendant thiophenyl moiety, were synthesized and characterized using standard spectroscopic techniques (FT-IR, UV-Vis, MS) and elemental analysis. C

This paper models “no war, no peace” situations in a game theoretical framework where two countries are engaged in a standoff over a military sector. The first main objective is to identify rational grounds for such situations and, more precisely, explicit equilibria that leads to such situations. It is demonstrated that both countries get the same payoff from being in this continuous state of per

More than 20 million Americans are affiliated with Multi-Level Marketing firms (MLMs), but there is little empirical evidence on who participates in this controversial part of today's labor market. We link data on 350,000 individuals cited in an FTC settlement with one of the largest MLMs to detailed county-level information. We find that participation is greater in areas with higher median income

The Grönhögen-2015 core drilling on southern Öland, Sweden, penetrated 50.15 m of Cambrian Series 3, Furongian and Lower–Middle Ordovician strata. The Cambrian succession includes the Äleklinta Member (upper Stage 5) of the Borgholm Formation and the Alum Shale Formation (Guzhangian–Tremadocian). Agnostoids and trilobites allowed subdivision of the succession into eight biozones, in ascending orde

This article aims to produce an analysis of the politicization of the citizens after Spain’s Indignados movement from a citizenship framework. The article suggests that claiming the right to the city involves more than issues of access to urban amenities: it is also about claiming the right to participate in the formation and transformation of the city and the right to appropriate the city center.

Overweight and obesity are increasing worldwide, but the extent in breast cancer patients is unknown. The two aims were to study secular trends in preoperative body mass index (BMI), waist circumference, and breast volume and their impacts on clinical outcome. BMI, waist circumference, and breast volume were measured preoperatively in 24–99-year-old primary breast cancer patients (n = 640) in Swed

Metallurgical debris is by far the most informative source material for studying the metal craftsmanship of the past. In comparison to the finished objects, which has attracted far more attention in archaeological research, debris material are more or less confined to the original workshop sites and hence provide direct evidence as to production volume and quality, site organization, artisanal ski

Extracellular electron transfer (EET) in microbial cells is essential for certain biotechnological applications and contributes to the biogeochemical cycling of elements and syntrophic microbial metabolism in complex natural environments. The Gram-positive lactic acid bacterium Enterococcus faecalis, an opportunistic human pathogen, is shown to be able to transfer electrons generated in fermentati

Return to Kashgar – the Jarring Collection of Uyghur Manuscripts Kashgar was a major crossroads for trade and culture along the Eurasian Silk Route for thousands of years, a place where Turkic, Persian, Arab, Chinese and other groups interacted. The Lund University Library is privileged to hold some 600 handwritten books from the sixteenth to the twentieth centuries from cities in this region like

Climate change projections show that temperature and precipitation increases can alter the exchange of greenhouse gases between the atmosphere and high latitude landscapes, including their freshwaters. Dissolved organic carbon (DOC) plays an important role in greenhouse gas emissions, but the impact of catchment productivity on DOC release to subarctic waters remains poorly known, especially at re

Background: Cadmium bioaccumulates in the body and causes several adverse health effects. Understanding the primary sources of exposure is critical in order to implement effective prevention measures. Methods: We included 454 adults enrolled in the Florence cohort of the European Prospective Investigation into Cancer and Nutrition (EPIC) during 1992–98. At enrolment, information was collected on d

Groundwater quality and quantity are two major challenges in arid and semi-arid regions, due to their critical roles in sustainable agricultural development. Irrigated lands are spread all over Urmia Lake's surrounding plains in Iran. Due to the risk of saltwater intrusion as a result of over-exploitation from groundwater resources, it is important to monitor the groundwater quality and quantity t

Thermal properties of pure tungsten, irradiated in the Swiss neutron spallation source at the Paul Scherrer Institut, have been studied in the temperature range 25–500 °C. Disk-shaped specimens were prepared from a tungsten sheet which was irradiated with high energy protons and spallation neutrons. The specimens tested in this work received total damages of maximum 3.9 and 5.8 dpa at average irra

The concept of circular business models has been identified as an important enabler for companies moving towards circular practices. Circular business models help to prolong lifetimes of products and parts through successive cycles of reuse, repair, remanufacturing and closing material loops. To realise economic viability and reductions in environmental impacts from innovating towards a circular b