The hydride iridium pincer complex [(PCyP)IrH2 ] (PCyP=cis-1,3-bis[(di-tert-butylphosphino)methyl]cyclohexane, 1) reveals remarkably solvent-dependent hydride chemical shifts, isotope chemical shifts, JHD and T1 (min), with rHH increasing upon moving to more polar medium. The only known example of such behaviour (complex [(POCOP)IrH2 ], POCOP=2,6-(tBu2 PO)2 C6 H3 ) was explained by the coordinatio

Marriage fields - the geographical areas where people meet to partner - traditionally tend to be relatively small and local. Increasing international travel and the use of the internet have broadened the geographical opportunity structure of potential partners. This increases the chances of meeting a partner from abroad, possibly resulting in a rise in international marriage migration. This paper

BACKGROUND: Diabetes is a major threat to public health in the United States and worldwide. Understanding the role of environmental chemicals in the development or progression of diabetes is an emerging issue in environmental health. OBJECTIVE: We assessed the epidemiologic literature for evidence of associations between persistent organic pollutants (POPs) and type 2 diabetes. METHODS: Using a Pu

We have studied solar variations during the Holocene (i.e., last similar to 11,700 yr) by combining a new model of the Earth's dipole moment with C-14 data from the IntCal04 record and 10 Be data from the GRIP ice core. Joint spectral analysis of the two nuclide records suggests that the periodic behavior of the Sun was particularly pronounced between 6000-4500 yr BP and 3000-2000 yr BP, with domi

Abstract in UndeterminedRelevant source area of pollen (RSAP) and pollen productivity for 11 key taxa characteristic of the pasture woodland landscape of the Jura Mountains, Switzerland, were estimated using pollen assemblages from moss polsters at 20 sites. To obtain robust pollen productivity estimates (PPEs), we used vegetation survey data at a fine spatial-resolution (1 x 1 m(2)) and randomize

The rationale for thrombolysis, the most promising pharmacological approach in acute ischaemic stroke, is centred on the principal cause of most ischaemic strokes: the thrombus that occludes the cerebral artery, and renders part of the brain ischaemic. The occluding thrombus is bound together within fibrin. Fibrinolysis acts by activation of plasminogen to plasmin; plasmin splits fibrinogen and fi

To any model of brain function, the variability of neuronal spike firing is a problem that needs to be taken into account. Whereas the synaptic integration can be described in terms of the original Hodgkin-Huxley (H-H) formulations of conductance-based electrical signaling, the transformation of the resulting membrane potential into patterns of spike output is subjected to stochasticity that may n

Popular Abstract in Swedish Celler som har förmågan att ge upphov till nästan alla typer av mogna celler i en organism kallas för pluripotenta stamceller. Förutom deras förmåga att bilda olika specialiserade celltyper har pluripotenta stamceller även den unika förmågan att genomgå ett obegränsat antal celldelningar. Under utvecklingen av en organism genomgår pluripotenta stamceller en process somDuring direct cellular reprogramming, forced expression of key transcription factors (TFs) directly converts one terminally differentiated cell type into that of another fate, exemplified in this theses by the conversion of fibroblasts into functional induced neurons (iNs). Direct conversion of mouse fibroblasts to functional neurons was established in 2010, and the starting point of my doctoral

Context-aware applications generally need to retrieve various kinds of dynamic context data from a large number of context sources. A middleware managing context sources must provide an efficient context lookup mechanism to ease application development. In this paper, we categorize the context sources as operating spaces and propose semantic peer-to-peer overlays over these spaces to accelerate dy

Spectroscopic Photoemission and Low Energy Electron Microscopy (SPELEEM) is a very powerful and diverse microscopy technique for the investigation of surfaces, interfaces, buried layers and nanoscale objects like nanoparticles and nanowires. The many significant results from photoemission Electron microscopy (PEEM) in recent years are linked with the exploitation of advanced light sources such as

A method of using benzenesulfonates and imidazylates as leaving groups at the secondary C3 galactopyranose carbon, instead of the commonly used less stable triflate leaving group, to facilitate scale-up and improve reproducibility is disclosed. The benzenesulfonates and imidazylates were proven to be significantly more stable than the corresponding triflates and the method was used to devise an im

Background: The observation of differences in the way apparently similar patients are treated from one health care setting to another, i.e., practice variation, have been recognized in numerous studies. The variations across the health care settings have been shown to exist for different outcomes. However, any measurement of any system will reveal some form of variation and this normal inevitable

Context. The performance of interferometers has been much increased over the past ten years. But the number of observable objects is still limited by the low sensitivity and imaging capability of the current facilities. Studies have been conducted with the aim to propose a new generation of interferometers. Aims. The Carlina concept studied at the Haute-Provence Observatory consists of an optical

The central question of the dissertation is whether and how African Caribbeans in the Danish West Indies identified themselves with African ethnic groups. The dissertation discusses if and how such identifications played a role in the social life of African Caribbeans and influenced how new social networks developed in the colony. The dissertation is shaped as a micro study focusing on members of the

Repeated exposure to certain low molecular weight (LMW) chemical compounds may result in development of allergic reactions in the skin or in the respiratory tract. In most cases, a certain LMW compound selectively sensitize the skin, giving rise to allergic contact dermatitis (ACD), or the respiratory tract, giving rise to occupational asthma (OA). To limit occurrence of allergic diseases, efforts

Background: Cerebral ischemia results in enhanced expression of contractile cerebrovascular receptors, such as endothelin type B (ETB), 5-hydroxytryptamine type 1B (5-HT1B), angiotensin II type 1 (AT(1)) and thromboxane (TP) receptors in the cerebral arteries within the ischemic area. The receptor upregulation occurs via activation of the mitogen-activated protein kinases (MAPK) pathway. Previous