Carbon dioxide ion dissociations after inner shell excitation and ionization: The origin of site-specific effects.
Multi-coincidence experiments with detection of both electrons and ions from decay of core-excited and core-ionized states of CO2 confirm that O2 (+) is formed specifically in Auger decay from the C1s-π* and O1s-π* resonances. Molecular rearrangement occurs by bending in the resonant states, and O2 (+) is produced by both single and double Auger decay. It is suggested that electron capture by C(+)
