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A Catalytic and Mechanistic Investigation of Palladium-Phosphine Catalysed Aqueous Hydroxycarbonylation. Steric and Electronic Properties of the Ligands

Popular Abstract in Swedish Utvecklingen av säkrare och mer miljövänliga processer är en av de största utmaningarna som den kemiska industrin står inför. I det här sammanhanget är katalys i tvåfassystem, bestående av vatten och organiska lösningsmedel, av största intresse eftersom den möjliggör en enkel återvinning av katalysatorn samtidigt som den minskar skadliga utsläpp och kostnader för återviThe steric and electronic properties of eight water-soluble phosphines (1-8) were investigated by different methods. Phosphines 1-6 were tested as ligands in palladium catalysed hydroxycarbonylation of styrene. In line with the proposal that a ligand with low basicity should facilitate nucleophilic attack of water on the acyl complex, the electron rich {4 - [Bis(2 - diethylaminoethyl)] - aminobenz

A systematic approach for identifying lean and green improvements related to packaging material in assembly

One significant environmental impact from assembly operations includes packaging material use and subsequent waste generation. Although current practice involves reduction of unnecessary materials handling, there is potential to adapt packaging material in order to simultaneously improve the environmental performance and reduce cost in a “lean and green” mindset. Hence, with increased emphasis on

On Tailbiting Codes from Convolutional Codes

Popular Abstract in Swedish Denna avhandling behandlar en speciell typ av felrättande koder som kallas tailbitingkoder. Syftet med en felrättande kod är att korrigera fel som kan uppkomma på grund av brus och störningar då digital information överförs från sändare till mottagare.Tailbiting is a method to terminate convolutional codes into block codes. We call these block codes tailbiting codes. This thesis focuses on the encoding of tailbiting codes. The tailbiting method is carefully investigated. Conditions for when the tailbiting method fails are given, and methods for the proper initialization of the encoder are presented. Furthermore, the minimum distances of the tai

LES of the flow and acoustics generated by a wing installed aircraft propeller running in the vicinity of the ground

A study on the noise generated by a subsonic four bladed propeller installed on a wing of an aircraft near the ground is presented. The method used is based on an acoustical analogy developed by Ffowcs Williams and Hawkings. Computations of the flow field are performed using LES with the incompressible fluid assumption, while the noise is evaluated using a non-homogeneous wave equation. The aim is

Photochemistry of Eumelanin Precursors Role of Excited State Proton Transfer for UV Photoprotection

Popular Abstract in Swedish Melanin är ett pigment som finns i många olika slags vävnader. I hud och hår finns två slags melanin, pheomelanin som är typiskt för rödhåriga personer och eumelanin som finns i större mängd i mörkt hår och hud. Konstaterad korrelation mellan hudcancer och solexponering motiverar forskarna att förstå mer om melanin och dess växelverkan med UV-ljus. Man vet att rödhårigaMelanin is an epidermal pigment commonly known to give darker skin coloration under sun exposure. It is also present in the hair, eyes, inner ear and brain. The first function of epidermis melanin is believed to be photoprotective against harmful ultraviolet (UV) light, but the recent increase of skin cancer correlated to an increase of sun exposure questions the properties of melanin. Its presenc

Effects of minor phrasing variations in traffic-related questionnaires - Comparison of objective equivalences and respondents' subjective statements

This paper examines questionnaire-related issues of variations in the wording of questions and the objective accuracy of the response, in terms of three traffic-related phenomena (accident frequency, incident frequency, and speeding). ca. 900 survey respondents, living along four major arterial streets in Malmö, Sweden, estimated the occurrence of the phenomena in question. The dispatch consisted

Noncollinear magnetoconductance of a quantum dot

We study theoretically the linear conductance of a quantum dot connected to ferromagnetic leads. The dot level is split due to a noncollinear magnetic field or intrinsic magnetization. The system is studied in the noninteracting approximation, where an exact solution is given, and, furthermore, with Coulomb correlations in the weak tunneling limit. For the noninteracting case, we find an antireson

On lumbar spine stabilization

Popular Abstract in Swedish Steloperation, fusion, i ryggen introducerades på 1910-talet som behandling vid tuberkulos med engagemeng av kotpelaren och sekundära smärtor/ deformitet. Senare applicerades tekniken på ryggfrakturer, skolioser och sedan 30-talet även på patienter med lumbala smärttillstånd med degenerativa förändringar. Smärtsam rörlighet eller överrörlighet i ledförbindelserna mellan71 consecutive posterolateral lumbar fusions without decompression or internal fixation were evaluated with a mean follow-up time of 3.5 (2-7) years. The diagnoses were spondylolysis-olisthesis in 43 cases, degenerative disc disease and/or facet joint arthrosis in 16 cases and pain post laminectomy/ decompression in 12 cases. 54/70 patients had a solid fusion. In the group with spondylolysis-olist

Facilitating IS capability – towards a new perspective on governance

It has been suggested that those organizations which have greatest competitive success are those in which information systems strategy is seen as integral to overall business strategy. Thus, the CIO is seen as a full member of the management team, and not as someone presiding over a separate functional area which provides a service to the rest. There is a need therefore for businesses to avoid suc