Heterogeneities and Emissive Defects in MAPbI3 Perovskite Revealed by Spectrally Resolved Luminescence Blinking
The fate of excited charge carriers in metal halide perovskite semiconductors is influenced by energetic disorder and defects. Here, photoluminescence (PL) blinking is used to probe metastable nonradiative (NR) centers and the nanoscale energy landscape. Temporal activation of an NR center creates a local region with increased NR recombination. Activation and deactivation of this local PL quenchin