Reversed Hysteresis during CO Oxidation over Pd75Ag25(100)
CO oxidation over Pd(100) and Pd75Ag25(100) has been investigated by a combination of near-ambient-pressure X-ray photoelectron spectroscopy, quadrupole mass spectrometry, density functional theory calculations, and microkinetic modeling. For both surfaces, hysteresis is observed in the CO2 formation during the heating and cooling cycles. Whereas normal hysteresis with light-off temperature higher