Highly mobile iron pool from a dissolution-readsorption process
Oxalate (C(2)O(4)(2-)) acts synergistically on the dissolution of goethite (alpha-FeOOH) in the presence of siderophores that are secreted by plants and microorganisms to sequester iron. We report here the first in situ molecular-scale observations of synergistic ligand-promoted dissolution processes. We show that there are conditions under which oxalate promotes goethite dissolution, but dissolve