Hexafluorophosphates of chlorotris(dimethyl sulfide)platinum(II) and bromotris (dimethyl sulfide)platinum(II)
The title compounds, chlorotris(dimethyl sulfide-kappaS)platinum(II) hexafluorophosphate, [PtCl(C2H6S)3]PF6, and bromotris(dimethyl sulfide-kappaS)platinum(II) hexafluorophosphate, [PtBr(C2H6S)3]PF6, are isomorphous and are composed of [PtX(dms)3]+ complex cations (X = Cl and Br, and dms is dimethyl sulfide) and PF6- anions. The Pt atom is coordinated by three S atoms and one X atom in
