Quantifying the trans influence of triphenylarsine. Crystal and molecular structures of cis-[PtCl2(SMe2)(AsPh3)] and cis-[PtCl2(AsPh3)(2)]center dot CHCl3
Reaction between a mixture of cis-trans-[PtCl2(SMe2)(2)] and 1 eqiv. AsPh3 in chloroform gives Cis-[PtCl2(SMe2)(AsPh3)] crystallizing in P2(1)/n with a = 10.397(2), b = 14.876(3), c = 13.956(3) Angstrom, beta = 90.86(3)degrees and Z = 4. Selected geometrical parameters are Pt-As 2.3531(10), Pt-S 2.262(2), Pt-Cl (trans to S) 2.301(2), Pt-Cl (trans to As) 2.328(2) Angstrom and S-Pt-As 88.85(6), S-Pt
