High-Pressure Stopped-Flow Study of Kinetics and Mechanism for Complex Formation Reactions of Tetraaquapalladium(II) and -Platinum(II) with Thioethers in Aqueous Solution
Complex formation between Pd(H2O)42+ and Pt(H2O)42+ and the thioethers Me2S, Et2S, 1,4-dithiane, and 1,4-thioxane has been studied as a function of temperature (278-308 K) and pressure (0.1-200 MPa) by use of stopped-flow and conventional spectrophotometry in an aqueous 1.00 M perchloric acid medium. The rate constants k1 for complex formation are similar for the four thioethers, varying only betw