Ammoxidation of Toluene by YBa2Cu3O6 + x and Copper Oxides. Activity and XPS Studies
The catalytic activities of YBa2Cu3O6+x and copper oxides have been studied in the ammoxidation of toluene. At low oxygen pressures, over YBa2Cu3O6+x selective ammoxidation to benzonitrile occurs, whereas at high pressures, only total combustion of toluene to carbon oxides is observed. X-ray photoelectron spectroscopy (XPS) analysis of YBa2Cu3O6+x catalysts indicates predominance of Cu(I) states u