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Synthesis, characterisation and ion-binding properties of oxathiacrown ethers appended to [Ru(bpy)2]2+. Selectivity towards Hg2+, Cd2+ and Pb2+

A series of complexes with oxathiacrown ethers appended to a [Ru(bpy)2]2+ moiety have been synthesized and characterised using 1H NMR, 13C NMR, IR, electronic absorption and emission spectroscopies, mass spectrometry and elemental analyses. The complexes exhibit strong MLCT luminescence bands in the range 608-611 nm and one reversible metal centred oxidation potential in the range 1.00-1.02 V. The

Housing taxation in the Netherlands

Houses are prominent in many taxes in the Netherlands. In this chapter we analyze the situation of Dutch housing taxation in local and national taxes. We show that both are intertwined because of the use of one value which is determined at the local level, but used at the national level as well. We briefly discuss the balance between local and national taxation in the Netherlands, the relatively l

Inorganic Ions Assisted Anisotropic Growth of CsPbCl3 Nanowires with Surface Passivation Effect

All-inorganic halide perovskite nanowires (NWs) exhibit improved thermal and hydrolysis stability and could thus play a vital role in nanoscale optoelectronics. Among them, blue-light-based devices are extremely limited because of the lack of a facile method to obtain high-purity CsPbCl3 NWs. Herein, we report a direct and facile method for the synthesis of CsPbCl3 NWs assisted by inorganic ions t

Towards a material politics of socio-technical transitions : Navigating decarbonisation pathways in Malmö

As the politics of climate change shift from the design of international institutions to the pursuit of decarbonisation across multiple sites, researchers are increasingly calling attention to the geography and politics of transitions. We suggest that recent work has so far been limited by its rather incongruous focus on power as a capacity held by individual agents on the basis of the resources w

A suboptimal array of options erodes the value of CAP ecological focus areas

As a part of the greening of the EU's Common Agricultural Policy in 2013, Ecological Focus Areas (EFA) became mandatory for many European farmers, with the aim to enhance on-farm biodiversity. However, their effects on biodiversity have been disputed. In this interdisciplinary effort, we assessed the effects of current and alternative formulations of EFA regulations in Sweden. By complementing eco

The Emerging Role of Calcium-activated Chloride Channel Regulator 1 in Cancer

Calcium-activated chloride channel regulator 1 (CLCA1) belongs to a group of secreted self-cleaving proteins, which activate calcium-dependent chloride channels. CLCA1 has been shown to participate in the pathogenesis of inflammatory airway diseases such as asthma. Recently, additional functions of CLCA1 have been unveiled, including its metalloprotease property and involvement in mucus homeostasi

Non-binary phase gratings for x-ray imaging with a compact Talbot interferometer

X-ray imaging using a Talbot-Lau interferometer, consisting of three binary gratings, is a well-established approach to acquire x-ray phase-contrast and dark-field images with a polychromatic source. However, challenges in the production of high aspect ratio gratings limit the construction of a compact setup for high x-ray energies. In this study we consider the use of phase gratings with triangul

Out-of-hospital cardiac arrest at place of residence is associated with worse outcomes in patients admitted to intensive care : a post-hoc analysis of the Targeted Temperature Management trial

BACKGROUND: The majority of out-of-hospital cardiac arrests (OHCAs) occur at place residence, which is associated with worse outcomes in unselected prehospital populations. Our aim was to investigate whether location of arrest was associated with outcome in a selected group of initial survivors admitted to intensive care.METHODS: This is a post-hoc analysis of the Targeted Temperature Management a

Master equation approach to DNA breathing in heteropolymer DNA

After crossing an initial barrier to break the first base-pair (bp) in double-stranded DNA, the disruption of further bps is characterized by free energies up to a few kBT. Thermal motion within the DNA double strand therefore causes the opening of intermittent single-stranded denaturation zones, the DNA bubbles. The unzipping and zipping dynamics of bps at the two zipper forks of a bubble, where

Blinking statistics of a molecular beacon triggered by end-denaturation of DNA

We use a master equation approach based on the Poland–Scheraga free energy for DNA denaturation to investigate the (un)zipping dynamics of a denaturation wedge in a stretch of DNA that is clamped at one end. In particular, we quantify the blinking dynamics of a fluorophore–quencher pair mounted within the denaturation wedge. We also study the behavioural changes in the presence of proteins that se

Angelic humans, glorious flesh : Jerome's reception of Origen's teachings on the resurrection body

One of the most important theological questions in the first Origenist controversy was that of the resurrection of the dead. Jerome accused both Origen and contemporary “Origenists” of speaking only of the resurrection of the body, and not of the flesh, and he claimed that an idea of resurrection without the flesh could not guarantee the identity between the body living on earth and the resurrecte

Mao’s Homeworld(s) : A Comment on the Use of Propaganda Posters in Post-War China

Within cognitive science, narratives are regarded as crucial and fundamental cognitive instruments or tools. As Roger Schank suggests, the identity of (sub-)cultures is to a considerable extent based upon the sharing of narrative structures (Schank. 1995. Tell me a story: Narrative and intelligence. Evanston, IL: Northwestern University Press.). According to Schank, culturally shared stories, as d

Violations of Dashen's theorem

The electromagnetic contribution to the K+-K0 mass difference is calculated in the 1 Nc approach including the SU(3) breaking contributions due to a non-zero strange quark mass. The short-distance contribution can be unambiguously determined in terms of the known parameters of the next-to-leading order chiral Lagrangian. The long distance part is estimated using the 1 Nc approach by Bardeen et al.