Synthesis, characterisation and ion-binding properties of oxathiacrown ethers appended to [Ru(bpy)2]2+. Selectivity towards Hg2+, Cd2+ and Pb2+
A series of complexes with oxathiacrown ethers appended to a [Ru(bpy)2]2+ moiety have been synthesized and characterised using 1H NMR, 13C NMR, IR, electronic absorption and emission spectroscopies, mass spectrometry and elemental analyses. The complexes exhibit strong MLCT luminescence bands in the range 608-611 nm and one reversible metal centred oxidation potential in the range 1.00-1.02 V. The