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Cyclometalation reactions on rhodium(I). Evidence for a chelate effect and competing C-H and C-O oxidative additions

The ligand Ph2PC6H4(CH2N(Me)CO(Et)) reacts with (bis(diphenylphosphino)butane) (2,5-norbornadiene)rhodium tetrafluoroborate (2a) and (bis(diphenylphosphino)ethane)(2,5-norbornadiene) rhodium tetrafluoroborate (2b) at room temperature in the presence of hydrogen to displace the norbornadiene and give the chelate complexes 3a,b, in which the phosphorus and the oxygen atoms are coordinated to give an

Kℓ4 decays and the low-energy expansion

Tha amplitudes for the Kℓ4 decays are calculated to next-to-leading order in Chiral Perturbation Theory. These are then compared with the available experimental results on these decays. The values of the parameters L1, 2, 3 previously determined from ππ scattering are compared with those obtained here. A short overview of the determination of the parameters of Chiral Perturbation Theory is include

Standardization as an Organizational Capability : Examples from a Global Player in the Information and Communication Technology Industry

This chapter examines the organizational capabilities that firms develop in order to influence and adapt to standards. Standards are voluntary rules or guidelines developed by standard-setting organizations or consortia in order to promote compatibility/interoperability, minimum quality, variety reduction, and information. The authors argue that firms develop specific capabilities for assessing wh

Cardiometabolic Polygenic Risk Scores and Osteoarthritis Outcomes : A Mendelian Randomization Study Using Data From the Malmö Diet and Cancer Study and the UK Biobank

Objective: To investigate the causal role of cardiometabolic risk factors in osteoarthritis (OA) using associated genetic variants. Methods: We studied 27,691 adults from the Malmö Diet and Cancer Study (MDCS) and replicated novel findings among 376,435 adults from the UK Biobank. Trait-specific polygenic risk scores for low-density lipoprotein (LDL) and high-density lipoprotein (HDL) cholesterol

Mechanical Properties of Boron Phosphides

Microstructure and mechanical properties of bulk polycristalline boron phosphides (cubic BP and rhombohedral B12P2) have been studied by scanning electron microscopy and micro- and nanoinden-tation. The obtained data on hardness, elastic properties and fracture toughness clearly indicate that both phosphides belong to a family of hard phases and can be considered as prospective binders for diamond

Digital clients : An example of people production in social work

Digital work has become part of social workers’ daily routines in countries where digitalisation is on the agenda. As a consequence, documentation practices are expanding—on paper as well as digitally—and include reporting detailed statistics about client interventions, filling in digital forms, and fulfilling local and national performance measurement goals. Standardised formulas with tick-box an

Diversity and zoonotic potential of rotaviruses in swine and cattle across Europe

Group A rotaviruses can infect both humans and animals. Individual rotavirus strains can occasionally cross species barriers and might hereby contribute to the emergence of new genotypes in heterologous hosts. The incidence and impact of zoonotic rotavirus are not well defined, and one reason for this is a lack of data about strains circulating in suspected reservoir animal hosts. In this study we

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A case of acute hepatitis due to hepatitis E virus genotype 3 was diagnosed by serology and genomic sequencing. Phylogenetic analysis demonstrated a strain identical to one isolated from a Swedish pig, which supports the hypothesis that swine serves as reservoirs for HEV infection. The patient did not have any recent travel history, had experienced no contact with animals and the origin of the inf

Quark, lepton and neutrino masses in grand unified theories with local generation group

We investigate unified models where all small quantities in the fermion mass matrices are given in terms of one small ratio of symmetry breaking scales. We describe for a U(1) generation symmetry how the size of masses and mixings is determined, including possible contributions from heavy mirror quarks and leptons. This can be used for computerized model scanning. We search for realistic mass patt

Assessing potential vulnerability and response of fish to simulated avian predation after exposure to psychotropic pharmaceuticals

Psychotropic pharmaceuticals present in the environment may impact organisms both directly and via interaction strengths with other organisms, including predators; therefore, this study examined the potential effects of pharmaceuticals on behavioral responses of fish to avian predators. Wild-caught juvenile perch (Perca fluviatilis) were assayed using a striking bird model after a seven-day exposu

Intratunical injection of autologous adipose stromal vascular fraction reduces collagen III expression in a rat model of chronic penile fibrosis

Previous studies have shown that the injection of adipose stem cells and stromal vascular fraction(SVF) into the tunica albuginea (TA) during the inflammatory phase in a rat model of Peyronie’s disease(PD) prevented the development of TA fibrosis. Our aim was to investigate whether local injection of SVF can reduce established fibrosis in a rat model of chronic phase of PD. Eighteen-male 12-wk-old

Sverige kan leda en revolution i jordbruket

Sverige kan bli ledande i en radikal omställning av framtidens matproduktion. Genom forskning och utveckling av perenna livsmedelsgrödor kan vi aktivt främja en perenn revolution i jordbruket. Perenna grödor återkommer år efter år utan att behöva sås på nytt, skriver en rad forskare.

Graded error signals in eyeblink conditioning

Minimizing errors is an important aspect of learning. However, it is not enough merely to record if an error occurred. For efficient learning, information about the magnitude of errors is critical. Did my tennis swing completely miss the target or did I hit the ball, but not quite in the sweet spot? How can neurons – which have traditionally been thought of as binary units – signal the magnitude o