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1H NMR Kinetic Study of Dimethyl Sulfoxide Exchange on Tetrakis(dimethyl- sulfoxide)platinum(II) at Variable Temperature and Pressure : High-pressure NMR kinetics. 36.

The present report is a 'H NMR investigation of the dimethyl sulfoxide exchange on Pt(Me2S0)42+ as a function of temperature and pressure in CD3N02. Dimethyl sulfoxide is an ambidentate ligand, and the complex contains two 0-bonded and two S-bonded ligands that are exchanging with the free ligand at different rates. It is favorable to follow these exchanges in a non-coordinating diluent like nitro

Threats of projected changes in fire regime for newly affected areas in Europe and Northern Africa

Under climate change conditions, climatic wildfire danger could also increase in ecosystems not dominated by fires until now. This increasing trend could lead to more area burned in the future. We have developed an algorithm to map new fire-prone areas in Europe and Northern Africa that identifies grid points where a rare fire event is becoming the mean at the end of the 21st century. When applyin

Compressor design for silicon debug

The objective of this paper is to design a compressor for silicon debug that is suitable in an industrial Nexus environment. The compressor must operate in real-time and must be lossless. Important for the compressor is high compression ratio, low hardware cost and high throughput. We implemented the compression on an FPGA and we compared our implementation in terms of throughput and hardware cost

Litterära fabrikationer : JT LeRoy och Araki Yasusada - både lögn och fiktion

Litterära fabrikationer – det litterära fenomen som vanligen kallas ”bluff” eller ”bedrägeri” – har de senaste decennierna gett upphov till en moralisk och tolkningsteoretisk debatt av starkt polariserad karaktär. I centrum för problematiken står de omtvistade betydelserna av författarens identitet och intention, grundläggande litteraturteoretiska frågor som ställs på sin spets av texter som redan

Exclusive vector meson production with a leading neutron in photon-hadron interactions at hadronic colliders

In this paper, we study leading neutron production in photon-hadron interactions that take place in pp and pA collisions at large impact parameters. Using a model that describes the recent leading neutron data at HERA, we consider exclusive vector meson production in association with a leading neutron in pp/pA collisions at RHIC and LHC energies. The total cross sections and rapidity distributions

Mini-Dirac cones in the band structure of a copper intercalated epitaxial graphene superlattice

The electronic band structure of an epitaxial graphene superlattice, generated by intercalating a monolayer of Cu atoms, is directly imaged by angle-resolved photoelectron spectroscopy. The 3.2 nm lateral period of the superlattice is induced by a varying registry between the graphene honeycomb and the Cu atoms as imposed by the heteroepitaxial interface Cu/SiC. The carbon atoms experience a later

Calibrating a market model with stochastic volatility to commodity and interest rate risk

Based on the multi-currency LIBOR Market Model, this paper constructs a hybrid commodity interest rate market model with a stochastic local volatility function allowing the model to simultaneously fit the implied volatility surfaces of commodity and interest rate options. Since liquid market prices are only available for options on commodity futures, rather than forwards, a convexity correction fo

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short story by May Telmissani

Compound genetically engineered mouse models of cancer reveal dual targeting of ALK1 and endoglin as a synergistic opportunity to impinge on angiogenic TGF-β signaling

Angiogenesis occurs early in tumor development, sustains primary tumor growth and provides a route for metastatic escape. The TGF-β family receptors modulate angiogenesis via endothelial-cell specific pathways. Here we investigate the interaction of two such receptors, ALK1 and endoglin, in pancreatic neuroendocrine tumors (PanNET). Independently, ALK1 and endoglin deficiencies exhibited genetical

Solar control mechanisms for enhanced thermal comfort and daylight control of a fully glazed space

This paper deals with the need of developing a method that can assist designers to select appropriate solarcontrol mechanisms in highly glazed spaces, in order to provide enhanced daylight and views while avoidingoverheating. The development of the method is based on real life needs and was initiated by an actual projectthat we, as building physicists / façade consultants were called in to assist.

Environmental Integration in Competition and Free-Movement Laws

Environmental Integration in Competition and Free-Movement Laws engages in a comprehensive analysis of the obligation of Article 11 TFEU (integration of environmental protection requirements) in the three core areas of EU internal market law: competition, state aid, and free movement. It develops a theoretical framework for integrating environmental and other policies and compares how environmenta

Resampling Strategies to Estimate Mean Concentrations from Low SNR In Vivo MR Spectra

A resampling method for quantitative MRS is presented that retains absolute concentrations. Averaging the spectra from a subset improved the concentrationestimates via increased SNR. Using short-TE STEAM spectra from human thalamus, the influence of subset size was systematically studied and verifiedagainst conventional bootstrap re-sampling. Even small subsets provided considerably better signal-

Arthritis management in primary care - A study of physiotherapists' current practice, educational needs and adherence to national guidelines

Background: With an increasing number of patients with osteoarthritis (OA) and rheumatoid arthritis (RA) in primary care, our aim was to investigate arthritis-related practice in physiotherapy and to study adherence to evidence-based care. Methods: Seventy physiotherapists (PTs) working in primary care were emailed a questionnaire to investigate current practice and the number of roles assumed by

Role of aromatic amino acids in lipopolysaccharide and membrane interactions of antimicrobial peptides for use in plant disease control

KYE28 (KYEITTIHNLFRKLTHRLFRRNFGYT-LR), the representative sequence of helix D of heparin co-factor II, was demonstrated to be potent against agronomically important Gram-negative plant pathogens Xanthomonas vesicatoria and Xanthomonas oryzae, capable of inhibiting disease symptoms in detached tomato leaves. NMR studies in the presence of lipopolysaccharide provided structural insights into the mec