Partial Reduction of a Vanadia/Silica-Titania Catalyst with NH3 + NO at 473 K Studied by Electrical Conductance and ESR Measurements
Partial reduction of vanadia supported on silica-titania by NH3 + NO has been studied by electrical conductance and ESR measurements. The relationship between electrical conductance and degree of reduction was determined by oxidative and reductive titrations of V(IV) and V(V) species leached from catalyst samples which had been reduced to different levels. In situ monitoring of the steady-state V(
