Metastable Cd4Sb3 : A complex structured intermetallic compound with semiconductor properties
The metastable binary intermetallic compound Cd4Sb3 was obtained as polycrystalline ingot by quenching stoichiometric Cd-Sb melts and as mm-sized crystals by employing Bi or Sn fluxes. The compound crystallizes in the monoclinic space group Pn with a = 11.4975(5) Å, b = 26.126(1) Å, c = 26.122(1) Å, β = 100.77(1)°, and V = 7708.2(5) A,̊3. The actual formula unit of Cd4Sb3 is Cd13Sb10 and the unit
