Lewis acid promoted endocyclic cleavage of glycosides and related acetals
This thesis is a summary of five papers concerning endocyclic cleavage of glycosides and related acetals. Simple lactol ethers undergo endocyclic cleavage to give acyclic chain extended products on treatment with organoaluminium and organotitanium reagents. The first examples where organotitanium reagents induced alkylative endocyclic cleavage of carbohydrates is presented. The best conditions for