Kinetics and Mechanisms in the Ammoxidation of Toluene over a Titania TiO2(B)-Supported Vanadium Oxide Monolayer Catalyst. 1. Selective Reactions
A kinetic investigation of the ammoxidation of toluene was carried out over a TiO,(B)-supported vanadium oxide catalyst with a loading corresponding to a theoretical monolayer. The partial pressures of reactants toluene, oxygen, and ammonia were varied, and rates were measured for the formations of benzaldehyde and benzonitrile. By analysis of the rate dependencies on partial pressures of reactant