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Synthesis and Characterization of a Dinuclear Manganese(III,III) Complex with Three Phenolate Ligands

A dinuclear manganese complex ([Mn2L(m-OAc)2]PF6) has been synthesized, where L is the trianion of 2,6-bis{[(2-hydroxy-3,5-di-tert-butylbenzyl)(2-pyridylmethyl)amino]methyl}-4-methylphenol, a ligand with three phenolate groups. The two pseudo-octahedrally coordinated Mn ions are bridged via the two bidentate acetate ligands and the 4-methylphenolate group of the ligand. We have characterized the c

A high resolution AMS-injector for the Pelletron in Lund

A high resolution injector system has recently been installed at the Lund 3 MV tandem Pelletron accelerator. The new injector, designed mainly for Al-26 ions, will increase the experimental potential of the Lund AMS facility considerably. High quality energy- and mass-resolution is obtained by using a 90degrees spherical electrostatic analyzer followed by a 90degrees magnetic analyzer. The injecto

Association of free-prostate specific antigen subfractions and human glandular kallikrein 2 with volume of benign and malignant prostatic tissue

BACKGROUND. We investigated the association of different subfractions of prostate specific antigen (PSA) and human glandular kallikrein 2 (hK2), such as total PSA (tPSA), complexed PSA (cPSA), free PSA (fPSA), "single-chain Intact fPSA" (fPSA-I), "multi-chain nicked fPSA" (fPSA-N), and total hK2 with volumes of total prostate gland, transition zone (tz), and prostate cancer (PCa) tissue in patient

Polyelectrolyte complexes as a tool for purification of plasmid DNA background and development

The demand for highly purified plasmids in gene therapy and plasmid-based vaccines requires large-scale production of pharmaceutical-grade plasmid. Plasmid DNA was selectively precipitated from a clarified alkaline lysate using the polycation poly(N,N'-dimethyldiallylammonium) chloride which formed insoluble polyelectrolyte complex (PEC) with the plasmid DNA. Soluble PECs of DNA with polycations h

Fetal growth is not associated with early onset of severe retinopathy in type 1 diabetes mellitus

Reduced fetal growth has been suggested as a possible risk factor for diabetic nephropathy. The aim of the present study was to examine whether there could be an association also with rapidly progressing severe retinopathy in younger type 1 diabetic patients. Maternal pregnancy, as well as birth parameters of 27 type 1 diabetic patients with severe retinopathy diagnosis at a median age of 25 years

Mating duration and frequency in a pine sawfly

Newly emerged females of the European pine sawfly, Neodiprion sertifer Geoffroy (Hymenoptera: Diprionidae), were placed on pine twigs in the field and their behavior was recorded. Twenty to 25% of the females attracted wild males and mated on the day of release. One-third to one-half of these females remained and oviposited, while the rest disappeared from their twigs after mating. The mating freq

An Autoinflammatory Disease with Deficiency of the Interleukin-1-Receptor Antagonist

BACKGROUND Autoinflammatory diseases manifest inflammation without evidence of infection, high-titer autoantibodies, or autoreactive T cells. We report a disorder caused by mutations of IL1RN, which encodes the interleukin-1-receptor antagonist, with prominent involvement of skin and bone. METHODS We studied nine children from six families who had neonatal onset of sterile multifocal osteomyelitis

Trifunctional conjugation reagents. Reagents that contain a biotin and a radiometal chelation moiety for application to extracorporeal affinity adsorption of radiolabeled antibodies

A method of removing radiolabeled monoclonal antibodies (mAbs) from blood using a device external to the body, termed extracorporeal affinity-adsorption (EAA), is being evaluated as a means of decreasing irradiation of noncancerous tissues in therapy protocols. The EAA device uses an avidin column to capture biotinylated-radiolabeled mAbs from circulated blood. In this investigation, three trifunc

Comparison of the 2,2-azinobis-3-ethylbenzotiazoline-6-sulfonic acid (ABTS) and ferric reducing anti-oxidant power (FRAP) methods to asses the total antioxidant capacity in extracts of fruit and vegetables

A comparison was made on the use of two spectrophotometric methods, the ferric reducing antioxidant power (FRAP) method and the 2,2 '-azinobis-3-ethylbenzotiazoline-6-sulfonic acid (ABTS) method, for the measurement of the total antioxidant capacity (TAC) of plant foods. The correlations of TAC measured by the two methods were highly significant in both water-soluble (r(2) = 0.90) and water-insolu

Anticipation requires adaptation

To successfully interact with a dynamic world, our actions must be guided by a continuously changing anticipated future. Such anticipations must be tuned to the processing delays in the nervous system as well as to the slowness of the body, something that requires constant adaptation of the predictive mechanisms, which in turn require that sensory information be processed at different time-scales.

Despite high uptake efficiency, non-mycorrhizal Rumex acetosella increases available phosphorous in the rhizosphere soil, whereas Viscaria vulgaris, Plantago lanceolata and Achillea millefolium does not

The phosphorous (P) uptake efficiency, reduction of the soil extractable P, and the root morphology was determined for the four common grassland species Rumex acetosella, Viscaria vulgaris, Plantago lanceolata and Achillea millefolium in one pot cultivation and one microcosm experiment. Rumex acetosella produced more than tree times as much biomass as each of V. vulgaris, P. lanceolata and A. mill

Urbanicity of place of birth and symptoms of psychosis, depression and anxiety in Uganda

Background The mechanism underlying the association between urban birth/upbringing and increased schizophrenia risk is unknown. This study explored whether an urban effect might be present in a low-income country setting, where the 'urban' environment may have radically different components, for example urban architecture, pollution levels or social cohesion. Aims To investigate the potential asso

Glacial and climate history of the Antarctic Peninsula since the Last Glacial Maximum

During the Last Glacial Maximum (LGM), ice thickened considerably and expanded toward the outer continental shelf around the Antarctic Peninsula. Deglaciation occurred between >14 ka BP and ca. 6 ka BP, when interglacial climate was established in the region. Deglaciation of some local sites was as recent as 4-3 ka BP. After a climate optimum, peaking ca. 4-3 ka BP, a distinct climate cooling occu

Connectivity and performance of science-based firms

This paper addresses whether or not there is a relationship between a young science-based firm's patterns of connections and the associated resource flows, and its performance. Hypotheses derived from the literature are tested in relation to three performance indicators: inventiveness, innovativeness and employment. Analyzing a set of firms in Sweden, Ohio and Massachusetts, working with biocompat

A longitudinal study of material planning applications in manufacturing companies

Purpose-The paper seeks to describe the state-of-the-art, reasons for selecting various material planning methods, and modes of applying methods for initiating inventory replenishment of purchased items. It also identifies trends from 1993 to 2005. Design/methodology/approach-Empirical survey data are collected from Swedish manufacturing companies in 1993, 1999 and 2005. The MRP, re-order point, f