Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons
The coordination polymer [Fe(SCN)(2)(1,2-bis(4-pyridylmethylene)hydrazine)(2)](n) [Fe(phenanthroline)(3)](2n)(ClO4)(2n)center dot n1,2-bis(4-pyridylmethylene)hydrazine center dot 4nH(2)O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)(3)](2)bphz)(4+) units in the pores and disordered water and perchlorate anions. The s