Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).
The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S an