Synthesis and Crystal Structure of Tetrakis(dimethylsulfoxide)platinum(II) Bis(trifluoromethanesulfonate)
Crystals of Pt(DMSO)4(TFMS)2 have been prepared by dissolution of platinum(II) hydroxide in a solution of CF3SO3H in DMSO and subsequent evaporation. The structure was determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is PFull-size image (<1 K) with Z = 2, a = 8.630(2), b = 9.557(3), c = 16.659(3) Å, α = 73.33(2), β = 77.38(2) and γ = 79.19(3)°. The reCrystals of Pt(DMSO)4(TFMS)2 have been prepared by dissolution of platinum(II) hydroxide in a solution of CF3SO3H in DMSO and subsequent evaporation. The structure was determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is PFull-size image (<1 K) with Z = 2, a = 8.630(2), b = 9.557(3), c = 16.659(3) Å, α = 73.33(2), β = 77.38(2) and γ = 79.19(3)°. The re
