Theoretical kinetic study of the reactions between pyridyl radicals and O2
Reactions of the primary pyridine radicals, ortho-, meta-, and para-pyridyls with oxygen control the overall rate of pyridine oxidation. In the present work, the potential energy surfaces of o-, m-, and p-pyridyls + O2 previously developed by the authors have been employed for a systematic theoretical kinetic study of the rate constants of these reactions. The geometries of reactants, products, in
