Intermolecular interactions in hydrogen bonded 1:1 molecular complexes. A matrix isolation study.
A number of matrix isolated binary hydrogen bonded complexes with water as one of the components have been investigated with FTIR in the mid and far infrared regions. Water has been found to be the hydrogen bond donor in complexes with water, ammonia, dimethyl ether and acetone. With formamide two equally strong hydrogen bonds are formed one from water to the carbonyl oxygen and one from an amide