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Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands

The regioselectivity in the Rh catalysed 1,4-hydrosilylation of isoprene was investigated. Variation of solvents and temperature did not significantly affect the isomer distribution between tail-product (I) and head-product (II). The choice of ligands had the greater influence, where Rh-I-based catalysts with the strong electron withdrawing ligand CO favoured production of isomer II, while Rh-I ca

Om bokbindarnas bruk av träspån

In Sweden the use of wooden boards and sca’boards as binding material was custom until the middle of the 19th century. Sca’boards are found in all kinds of more or less expensive bindings with different covering materials; silk, parchment, leather and paper. During the 19th century they were mainly used in simple and cheap retail bindings destined for the peasantry. In this article the reasons for

Continuity of leisure participation from middle age to old age

Objectives. Continuity in habits, activities, and roles is important upon entering old age according to the continuity theory of aging. Few studies have investigated patterns of leisure participation over an extended period of time among older adults. This study examines changes in nine different leisure activities in a nationally representative sample of individuals followed over a 34-year period

Decreasing incidence of major amputation in diabetic patients: a consequence of a multidisciplinary foot care team approach?

The purpose of this retrospective study was to evaluate the changes in diabetes-related lower extremity amputations following the implementation of a multidisciplinary programme for prevention and treatment of diabetic foot ulcers in a 0.2 million population with a 2.4% prevalence of diabetes. All diabetes-related primary amputations from toe to hip from 1 January 1982 to 31 December 1993 were inc

3p -> 3d resonant photoemission spectroscopy of a TiO2 sub-monolayer grown on Al2O3

The valence band resonant photoemission spectra of a TiO2 sub-monolayer grown on an Al2O3 substrate have been measured throughout the Ti 3p absorption edge, i.e. at photon energies between 40 and 60 eV. The resonance process has been analysed in terms of constant initial state (CIS) curves, showing a peak at 49.5 eV photon energy, corresponding to a Fano-like resonant process. The Ti 3d contributi

Fasting insulin, calcium metabolism and the electrocardiogram in hypertensive subjects

Changes in both calcium and insulin metabolism have been described in essential hypertension. Low levels of plasma ionized calcium (Ca2+) and high levels of insulin have previously been associated with vascular complications and coronary heart disease. In the present study, indices of calcium metabolism and fasting serum insulin were related to electrocardiographic (ECG) variables in 58 patients w

Low-temperature irradiation effects in lithium orthosilicates

The emission spectra of lithium orthosilicates (Li4SiO4) ceramics have been measured in the range of 1.8-5.8 eV under irradiation by 6-30 eV photons or 1-30 keV electrons at 6-300 K. The tunnel recombination phosphorescence, as well as luminescence, stimulated by 1.5-2.5 eV photons has been detected in the sample preliminarily irradiated at 6 or 80 K. The main peaks of thermally stimulated lumines

Safe treatment of thiopurine S-methyltransferase deficient Crohn's disease patients with azathioprine

Thiopurine S-methyltransferase (TPMT) deficient patients develop life threatening haematotoxicity (for example, pancytopenia) when treated with a standard dose of azathioprine (AZA) and 6-mercaptopurine (6-MP) due to excessive accumulation of cytotoxic metabolites. At present, it is generally recommended that these patients should not receive AZA or 6-MP treatment for inflammatory bowel disease. W

Digital filters in adaptive time-stepping

Adaptive time-stepping based on linear digital control theory has several advantages: the algorithms can be analyzed in terms of stability and adaptivity, and they can be designed to produce smoother stepsize sequences resulting in significantly improved regularity and computational stability. Here, we extend this approach by viewing the closed-loop transfer map H-(φ) over cap: log (φ) over cap ba

Are found defects an indicator of software correctness? An investigation in a controlled case study

In quality assurance programs, we want indicators of software quality, especially software correctness. The number of found defects during inspection and testing are often used as the basis for indicators of software correctness. However, there is a paradox in this approach, since the remaining defects is what impacts negatively on software correctness, not the found ones. In order to investigate

Cystatin C, beta-2-microglobulin and beta-trace protein in pre-eclampsia

Background. An altered renal function is an essential component of the patho-physiology of pre-eclampsia. The plasma levels of low molecular mass proteins, e. g. beta-trace protein, beta-2-microglobulin and cystatin C, are increased in the third trimester of normal pregnancy. The plasma levels of cystatin C and beta-2-microglobulin are further increased in preeclampsia, and the cystatin C level ha

Elevinflytande i Lomma kommuns skolor (skolår 7-9). Sammanställning av empiriskt material insamlat genom kvalitativa intervjuer med elever, lärare och rektorer vid två olika skolor juni månad 2005

Föreliggande rapport handlar om demokrati, delaktighet och inflytande i två av Lomma kommuns grundskolor. Elevers rättigheter till inflytande finns föreskrivet i barnkonventionen, skollagen, kommunala styrdokument, samt i enskilda skolors lokala vardag. Vad innebär elevinflytande? Hur gestaltas elevinflytandet, formellt och informellt? Hur upplever elever möjligheterna till delaktighet i undervisn

Approximation and Online Algorithms with Applications in Computational Biology and Computational Geometry

The main contributions of this thesis are in the area of approximation and online algorithm design and derivation of lower bounds on the approximability for a number of combinatorial optimization problems with applications in computational biology and computational geometry. Approximation and online algorithms are fundamental tools used to deal with computationally hard problems and problems in wh

Towards an artificial model for Photosystem II: a manganese(II,II) dimer covalently linked to ruthenium(II) tris-bipyridine via a tyrosine derivative

In order to model the individual electron transfer steps from the manganese cluster to the photooxidized sensitizer P680+ in Photosystem II (PS II) in green plants, the supramolecular complex 4 has been synthesized. In this complex, a ruthenium(II) tris-bipyridine type photosensitizer has been linked to a manganese(II) dimer via a substituted l-tyrosine, which bridges the manganese ions. The trinu

Islam på svenska : tidskriften Salaam och islams globalisering

Popular Abstract in Swedish Avhandlingen beskriver och diskuterar de tidskrifter och böcker som muslimer i Sverige skrivit på svenska under 1900-talet. Framförallt gås innehållet i tidskriften Salaam - Islamisk Tidskrift (grundad 1986) igenom. Innehållet diskuteras i förhållande till hur islam har globaliserats de senaste tre decennierna. En slutsats är att Salaams skribenter har försökt att knytaThis dissertation focuses on written Islamic discourses in Swedish, especially the journal Salaam - Islamisk tidskrift. The journal first appeared in 1986 and is a part of the activities of Islamiska Informationsföreningen. From the beginning, Salaam has been edited by female converts to Islam in their twenties or early thirties. Female converts also account for a large number of the texts that ha

TNT leakage through sediment to water and toxicity to Nitocra spinipes

The fate and effects of 2,4,6-trinitrotoluene (TNT) at marine ammunition dumping sites are essentially unknown. The objective of this study was to examine the release from solid TNT to seawater when covered by sediment of two different types (sandy and fine-grained) and thickness (0, 1 2, and 4 cm), under different temperatures (5, 10, and 20 degrees C), and light conditions (ambient daylight and