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Modulations in the onoratoite system

The iodide form of the mineral onoratoite was synthesized, and like the Cl and Br based analogues, it displays super structure ordering, but for the iodide, the super structure is clearly incommensurate. Due to the poor quality of crystals attainable, the structure was solved by converting the solution of the Cl analogue to a super space formalism, and then using the structural elements from this

Structural model for octagonal quasicrystals derived from octagonal symmetry elements arising in β-Mn crystallization of a simple monatomic liquid

While performing molecular-dynamics simulations of a simple monatomic liquid, we observed the crystallization of a material displaying octagonal symmetry in its simulated diffraction pattern. Inspection of the atomic arrangements in the crystallization product reveals large grains of the β-Mn structure aligned along a common fourfold axis, with 45° rotations between neighboring grains. These 45° r

Helical chains of [MO5Cl] octahedra - Three compounds in the new family AEM2Te3O8Cl2 (AE = Ca, Sr and M = Co, Ni)

The compounds CaCo2Te3O8Cl2, SrCo2Te3O8Cl2 and SrNi2Te3O8Cl2 were synthesized via solid-gas reactions and investigated using single-crystal X-ray diffraction. While the compound CaCo2Te3O8Cl2 formed large enough single crystals to allow for a detailed structural analysis, crystals of the Sr-containing compounds yielded evidence that they are isostructural. CaCo2Te3O8Cl2 crystallizes in the monocli

Vacancy-ordering effects in AlB2-type ErGe2 - X (0.4 < x ≤ 0.5)

In the Er-Ge system, the compostion range ErGe2 to Er2Ge3 has been investigated. Eight samples were produced by arc melting of the elements, and analyzed using X-ray powder diffraction. Nine crystal structures were found to be present in the samples. The structures are described as a homologous series and presented within the superspace formalism using the superspace group X2/m(α0γ)0s, X represent

Structure of δ1-CoZn7.8 an example of a phason pinning-unpinning transformation?

The novel structure of the δ1 phase in the cobalt-zinc system was determined by single-crystal X-ray diffraction. The structure features fused double icosahedra linked by edge-and face-sharing. The δ1-CoZn7.8 structure is incommensurately modulated along the columnar b direction. The extent of the linear pentagonal antiprismatic intergrowth is limited to a maximum of two overlapping icosahedra bec

Expression of tSTAT3, pSTAT3 727 , and pSTAT3 705 in the epithelial cells of hormone-naïve prostate cancer

Background: The signal transducer and activator of transcription 3 (STAT3) pathway is observed to be constitutively activated in several malignancies including prostate cancer (PCa). In the present study, we investigated the expression of total STAT3 (tSTAT3) and two forms of activated phosphorylated STAT3 (pSTAT3 727 and pSTAT3 705 ) in tissue microarrays (TMA) of two cohorts of localized horm

Clinical protein science in translational medicine targeting malignant melanoma

Melanoma of the skin is the sixth most common type of cancer in Europe and accounts for 3.4% of all diagnosed cancers. More alarming is the degree of recurrence that occurs with approximately 20% of patients lethally relapsing following treatment. Malignant melanoma is a highly aggressive skin cancer and metastases rapidly extend to the regional lymph nodes (stage 3) and to distal organs (stage 4)

Acceptance and Use of Innovative Assistive Technologies among People with Cognitive Impairment and Their Caregivers : A Systematic Review

Cognitive impairments (CI), associated with the consequences of Alzheimer's disease and other dementias, are increasingly prevalent among older adults, leading to deterioration in self-care, mobility, and interpersonal relationships among them. Innovative Assistive Technologies (IAT) such as electronic reminders and surveillance systems are considered as increasingly important tools to facilitate

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Detta är den sjunde publikationen i en serie småskrifter som alla handlar om vetenskap och beprövad erfarenhet. Denna gång ligger fokus på socialtjänsten. I de tidigare skrifterna i denna serie har det framkommit hur viktigt be- greppet vetenskap och beprövad erfarenhet är för en rad verksamhetsområden, till exempel medicin, skola och poli- tik. Inte att förglömma begreppet eller begre

Why Was Unemployment so Low in Postwar Sweden? An Analysis with New Unemployment Data by Manufacturing Industry, 1935-1948

Sweden is often cited as one of the starkest examples of a country where corporatist policy structures and centralized wage bargaining produced remarkable economic and social outcomes in the postwar golden years. Not surprisingly, previous explanations for Sweden’s full employment period have emphasized this set of labor market institutions which was in place from the 1950s. Alternatively, tempora

Improved survival prognostication of node-positive malignant melanoma patients utilizing shotgun proteomics guided by histopathological characterization and genomic data

Metastatic melanoma is one of the most common deadly cancers, and robust biomarkers are still needed, e.g. to predict survival and treatment efficiency. Here, protein expression analysis of one hundred eleven melanoma lymph node metastases using high resolution mass spectrometry is coupled with in-depth histopathology analysis, clinical data and genomics profiles. This broad view of protein expres

The Behavior of Turbulent Heat Transfer Deterioration in Supercritical Hydrocarbon Fuel Flow Considering Thermal Resistance Distribution

To highlight the thermal management of the cooling system in an advanced engine, the flow and heat transfer characteristics of turbulent hydrocarbon fuel flow in a rectangular channel are numerically explored in detail. The severe condition of deteriorated behavior is investigated in the heat transfer process. Considering buoyancy force effects, a three-dimensional numerical model is established a

α-Cd13-xSb10 - The devil is in the details

A detailed study of the structure of α-Cd13-xSb 10 was performed using a high quality single crystal obtained from a cadmiumrich melt. The study clearly shows that this sample is cadmium-deficient, and should more properly be labelled α-Cd13-xSb10, but whether this is true in general for this phase, or if it is an effect of the precise conditions of synthesis remains unclear. Like for the similar

Single-crystal X-ray study of Ba2Cu2Te 4O11Br2 and its incommensurately modulated superstructure companion

Compounds containing lone-pair elements such as TeIV are very interesting from the structural point of view, as the lone-pair nonbonding regions create low-dimensional geometrical arrangements. We have synthesized two new compounds with these features - Ba2Cu2Te 4O11Br2 (I) and Ba2Cu 2Te4O11-δ(OH)2δBr 2 (II, δ ≈ 0.57) - as members of the AE-M-Te-O-X (AE = alkaline-earth metal, M = transition metal

All the disorder mechanisms in the 13:58 phases come together. Out of the modulated confusion rises the remarkable phase Ce12.60Cd 58.68(2)

The compound Ce12.60Cd58.68(2) is a metrically commensurate representative of the incommensurately modulated phase Ce 13Cd57+δ. It is most likely a lock-in phase. The structure, which was solved using seeding of the modulation from those positions most affected as well as direct solution by charge flipping, represents a rare case of ordering in a family of structures where disorder is the rule. Th