Atmospheric chemistry of cis-CF3CHCHF: Kinetics of reactions with OH radicals and O3 and products of OH radical initiated oxidation
Long path length FTIR-smog chamber techniques were used to measure k(OH + cis-CF3CHCHF) = (1.20 ± 0.14) × 10−12 and k(O3 + cis-CF3CHCHF) = (1.65 ± 0.16) × 10−21 cm3 molecule −1 s−1 in 700 Torr of N2/O2 diluent at 296 K. The OH initiated oxidation of cis-CF3CHCHF gives CF3CHO and HCOF in molar yields which are indistinguishable from 100%. The atmospheric lifetime of cis-CF3CHCHF is determined by it
