On a TiNiSi-Type Superstructure: Synthesis, Crystal and Electronic Structures of CaAgGe and Its Mn-Substituted Derivative
The compound CaAgGe and its Mn-substituted derivative CaMn0.07Ag0.93Ge were synthesized by reaction of the element mixtures at high temperature. Their structures were refined from single-crystal X-ray diffraction data. CaAgGe crystallizes in the isomorphic (i(3)) superstructure of the TiNiSi type (CaCuGe type). The LMTO band structure calculations predicted the CaAgGe phase to be metallic. In addi
