Temperature effect on single chain MEH-PPV spectra
We report single molecule photoluminescence spectra of poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) in PMMA-matrix at 293 and 20 K with 90 s acquisition time. All spectra at 293 K are very similar, contrary to literature results with acquisition times < 5 s. We propose that fluctuations of conformations with distinct emission properties cause broadening of the spectra and
