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Effect of Internal Architecture on the Assembly of Soft Particles at Fluid Interfaces

Monolayers of soft colloidal particles confined at fluid interfaces are at the core of a broad range of technological processes, from the stabilization of responsive foams and emulsions to advanced lithographic techniques. However, establishing a fundamental relation between their internal architecture, which is controlled during synthesis, and their structural and mechanical properties upon inter

Dynamical properties of different models of elastic polymer rings : Confirming the link between deformation and fragility

We report extensive numerical simulations of different models of 2D polymer rings with internal elasticity. We monitor the dynamical behavior of the rings as a function of the packing fraction to address the effects of particle deformation on the collective response of the system. In particular, we compare three different models: (i) a recently investigated model [N. Gnan and E. Zaccarelli, Nat. P

Charge affinity and solvent effects in numerical simulations of ionic microgels

Ionic microgel particles are intriguing systems in which the properties of thermo-responsive polymeric colloids are enriched by the presence of charged groups. In order to rationalize their properties and predict the behaviour of microgel suspensions, it is necessary to develop a coarse-graining strategy that starts from the accurate modelling of single particles. Here, we provide a numerical adva

Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics

Soft colloids are increasingly used as model systems to address fundamental issues such as crystallization and the glass and jamming transitions. Among the available classes of soft colloids, microgels are emerging as the gold standard. Since their great internal complexity makes their theoretical characterization very hard, microgels are commonly modeled, at least in the small-deformation regime,

Local voltage control in a low voltage grid with high photovoltaic penetration

This thesis examines how active power control (Volt-Watt control) and reactive power compensation (Volt-VAr control) can help limit voltage increases on the low voltage grid due to high photovoltaic (PV), installations. Due to the large increase in interest to install small scale PV-systems within residential areas the Distribution System Operator E.ON, has noticed problems concerning high voltage

Fluctuating systems under cyclic perturbations : Relation between energy dissipation and intrinsic relaxation processes

This study focuses on fluctuating classical systems in contact with a thermal bath, and whose configurational energetics undergoes cyclic transformations due to interaction with external perturbing agents. Under the assumptions that the configurational dynamics is a stochastic Markov process in the overdamped regime and that the nonequilibrium configurational distribution remains close to the unde

Tuning the rheological behavior of colloidal gels through competing interactions

We study colloidal gels formed by competing electrostatic repulsion and short-range attraction by means of extensive numerical simulations under external shear. We show that, upon varying the repulsion strength, the gel structure and its viscoelastic properties can be largely tuned. In particular, the gel fractal dimension can be either increased or decreased with respect to mechanical equilibrium

Numerical insights on ionic microgels : Structure and swelling behaviour

Recent progress has been made in the numerical modelling of neutral microgel particles with a realistic, disordered structure. In this work we extend this approach to the case of co-polymerised microgels where a thermoresponsive polymer is mixed with acidic groups. We compare the cases where counterions directly interact with microgel charges or are modelled implicitly through a Debye-Hückel descr

Microgels Adsorbed at Liquid-Liquid Interfaces : A Joint Numerical and Experimental Study

Soft particles display highly versatile properties with respect to hard colloids and even more so at fluid-fluid interfaces. In particular, microgels, consisting of a cross-linked polymer network, are able to deform and flatten upon adsorption at the interface due to the balance between surface tension and internal elasticity. Despite the existence of experimental results, a detailed theoretical u

Modelling realistic microgels in an explicit solvent

Thermoresponsive microgels are polymeric colloidal networks that can change their size in response to a temperature variation. This peculiar feature is driven by the nature of the solvent-polymer interactions, which triggers the so-called volume phase transition from a swollen to a collapsed state above a characteristic temperature. Recently, an advanced modelling protocol to assemble realistic, d

Walk It Like You Talk It: En Kvalitativ Studie om Etiska AI-Strategier

Research question: How are organizations integrating ethical and strategic considerations into their approaches to AI implementation? Purpose: The purpose of this research is to systematically map ethical and strategic themes relevant to Artificial Intelligence Systems within the business context from a practitioner standpoint. This study aims to contribute to the understanding of this research fi

Minimal invasive LASER-resection vs. radiotherapy as primary treatment of early glottic cancer. A population-based study with, up to 16 years follow up of survival, rate of laryngectomy and voice function

BACKGROUND: Early glottic cancer can be treated with laser resection or radiotherapy. In an earlier study, we found that voice function after laser resection was inferior to that after radiotherapy.OBJECTIVES: This study was designed to determine if reduced margins at laser resection improved voice function without impairing oncologic results.METHOD: A total of 268 patients with previously untreat

Operator gender differences in major mechanical complications after central line insertions : a subgroup analysis of a prospective multicentre cohort study

BACKGROUND: A previous study on mechanical complications after central venous catheterisation demonstrated differences in complication rates between male and female operators. The objective of this subgroup analysis was to further investigate these differences. The hypothesis was that differences in distribution of predefined variables between operator genders could be identified.METHODS: This was

Optimization of pore geometry, pore density and membrane material for nanoelectroporation

Injektion av specifikt utvalt DNA i celler är en teknik som har många användningsområden, tillexempel i cell- och genterapier men också för att studera orsaker till olika sjukdomar som diabetes. Målet med att introducera DNA är att få cellen att bete sig på ett önskat sätt. Anledningen till detta kan vara för att antingen kunna använda cellen som en behandling mot cancer, eller för att åstadkomma Electroporation is a technique used to transfect cells, i.e. to introduce nucleic acids in cells. The method consists in applying a voltage over the cells which leads to the opening of pores in the cell membrane through which cargo can diffuse to the cell interior. If the cells are cultivated on top of nanopores or nanostraws, dielectric structures one can achieve nanoelectroporation when applying

Modelling UX Ori star eclipses based on spectral observations with the Nordic Optical Telescope − I. RR Tau

Based on observations obtained with the Nordic Optical Telescope (NOT) we investigate the spectral variability of the Herbig Ae star RR Tau. This star belongs to the UX Ori family, characterized by very deep fadings caused by the screening of the star with opaque fragments (clouds) of the protoplanetary discs. At the moments of such minima one observes strong spectral variability due to the fact t

Singular value decay of operator-valued differential Lyapunov and Riccati equations

We consider operator-valued differential Lyapunov and Riccati equations, where the operators B and C may be relatively unbounded with respect to A (in the standard notation). In this setting, we prove that the singular values of the solutions decay fast under certain conditions. In fact, the decay is exponential in the negative square root if A generates an analytic semigroup and the range of C ha

GPU acceleration of splitting schemes applied to differential matrix equations

We consider differential Lyapunov and Riccati equations, and generalized versions thereof. Such equations arise in many different areas and are especially important within the field of optimal control. In order to approximate their solution, one may use several different kinds of numerical methods. Of these, splitting schemes are often a very competitive choice. In this article, we investigate the