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Amorphous carbon filaments were synthesized by catalytic pyrolysis of propene over Pd3P colloids. The channel close to the center of the filaments usually contained particles, which were analyzed by analytical electron microscopy to be palladium. The palladium particles could be found anywhere along the filament. The carbon filaments were of two types and of different diameters, about 8-15 nm and
The photoluminescence of Mn2+ in ZnS:Mn2+ nanoparticles with an average size of 4.5 nm has been measured under hydrostatic pressure from 0 to 6 GPa. The emission position is red-shifted at a rate of -33.3+/-0.6meV/GPa, which is in good agreement with the calculated value of -30.4meV/GPa using the crystal field theory. (C) 2000 Elsevier Science B.V. All rights reserved.The photoluminescence of Mn2+ in ZnS : Mn2+ nanoparticles with an average size of 4.5 nm has been measured under hydrostatic pressure from 0 to 6 GPa. The emission position is red-shifted at a rate of −33.3±0.6 meV/GPa, which is in good agreement with the calculated value of −30.4 meV/GPa using the crystal field theory.
Coating Ti-based implants with bioactive materials promotes joining between the prostheses and the bone as well as increasing long-term implant stability. In the present work, the interface between Ti-6Al-4V and bioactive silicate glass coatings, prepared using a simple enameling technique, is analyzed. High-resolution transmission electron microscopy of the glass/alloy interface shows the formati
The Mn2+ emission wavelengths are at 591, 588, 581 and 570 nm, respectively, for the similar to 10, similar to4.5, similar to3.5 nm sized nanoparticles and the ZnS:Mn nanoparticles formed in an ultrastable zeolite-Y. To reveal the cause for the shift, the crystal field and phonon coupling were investigated. The results show that the predominant factor for the shift is the phonon coupling, whose st
A method for the simulation of electron diffraction patterns from partially ordered semiconductor compounds with CuPt-type ordering is proposed. The simulation procedure is based on the generation of two-dimensional model structures containing different types of imperfections. The defects are randomly dispersed in the structure and they are characterized by statistical parameters (density, average
Leaders’ debates have become a feature of contemporary election campaigning. While an historical feature of the US landscape, in the United Kingdom, they are a more recent phenomenon. The second UK 2015 general election leadership debate comprised seven candidates, of which three were women. Using qualitative thematic analysis and adopting the notion that gender is ‘performed’, we explore three fe
The emission bands of the 4.2, 3.2 and 2.6 nm sized ZnS:Eu2+ nanoparticles are peaking at 670, 580 and 520 nm, respectively. The emission of the 4.2 nm sized nanoparticles originates from the recombination of the Eu2+-bound exciton, while the emission of the 3.2 and 2.6 nm sized nanoparticles is from the Eu2+ intra-ion transition of 4f(6)5d(1)(t(2g))-4f(7). Possible mechanisms for the size depende
The structure of GP-zones in an industrial, 7xxx-series Al–Zn–Mg alloy has been investigated by transmission electron microscopy methods: selected area diffraction, conventional and high-resolution imaging. Two types of GP-zones, GP(I) and (II) are characterized by their electron diffraction patterns. GP(I)-zones are formed over a wide temperature range, from room temperature to 140–150°C, indepen
Sr-vacancy compensated Nb-doped SrTiO3 with the nominal composition Sr0.94Ti09Nb0.1O3 has been evaluated as part of a solid oxide fuel cell (SOFC) anode material in terms of redox stability, electrical conductivity, as well as electrochemical properties. Sr0.94Ti0.9Nb0.1O3 has been synthesized with a recently developed modified glycine-nitrate process. The synthesized powders have been calcined an
Nanowires offer unprecedented flexibility as nanoscale building blocks for future optoelectronic devices, especially with respect to nanowire solar cells and light-emitting diodes. A relatively new concept is that of charge carrier diffusion-induced light-emitting diodes, for which nanowires offer an interesting architecture by use of particle-assisted core-branch growth. The branches should be hoNanowires offer unprecedented flexibility as nanoscale building blocks for future optoelectronic devices, especially with respect to nanowire solar cells and light-emitting diodes. A relatively new concept is that of charge carrier diffusion-induced light-emitting diodes, for which nanowires offer an interesting architecture by use of particle-assisted core-branch growth. The branches should be ho
