Temperature Response of Charged Colloidal Particles by Mixing Counterions Utilizing Ca2+/Na+ Montmorillonite as Model System
The osmotic pressure and the aggregation of charged colloids as a function of temperature have been investigated using Monte Carlo and molecular dynamics simulations for different ratios of monovalent and divalent counterions. In the simulations the water is treated as a temperature-dependent dielectric continuum, and only the electrostatic interactions are considered. It was found that the temper
