Internal energy of photofragments studied by dispersed fluorescence spectroscopy
The fluorescence emission following inner-shell excitation of molecules has been analyzed in the wavelength region 300 nm≤λfluo≤1000 nm. The main contributions to the experimental spectrum are due to transitions of the parent molecules ionized in the outer valence shells as well as to the radiative decay of excited photofragments, mainly neutral and singly charged atoms. As an example, the dispers