Light induced manganese oxidation and long-lived charge separation in a Mn-2(II,II)-Ru-II (bpy)(3)-acceptor triad
The photoinduced electron-transfer reactions in a Mn-2(II.II)-R-II-NDI triad (1) ([Mn-2(bpmp)(OAc)(2)](+), bpmp = 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methyiphenolate and OAc = acetate, R-II = trisbipyridine ruthenium(II), and NDI = naphthalenediimide) have been studied by time-resolved optical and EPR spectroscopy. Complex 1 is the first synthetically linked electron donor-sensitizer-accept
