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Formation spectra of the EPR split signals from the S0, S 1, and S3 states in photosystem II induced by monochromatic light at 5 K

The interaction EPR split signals from photosystem II (PSII) have been reported from the S0, S1, and S3 states. The signals are induced by illumination at cryogenic temperatures and are proposed to reflect the magnetic interaction between YZ• and the Mn 4Ca cluster. We have investigated the formation spectra of these split EPR signals induced in PSII enriched membranes at 5 K using monochromatic l

The S0 state of the water oxidizing complex in photosystem II : pH dependence of the EPR split signal induction and mechanistic implications

Water oxidation in photosystem II is catalyzed by the CaMn4 cluster. The electrons extracted from the CaMn4 cluster are transferred to P680+ via the redox-active tyrosine residue D1-Tyr161 (YZ). The oxidation of YZ is coupled to a deprotonation creating the neutral radical YZ•. Light-induced oxidation of YZ is possible down to extreme temperatures. This can be observed as a split EPR signal from Y

pH dependent competition between YZ and YD in photosystem II probed by illumination at 5 K

The photosystem II (PSII) reaction center contains two redox active tyrosines, YZ and YD, situated on the D1 and D2 proteins, respectively. By illumination at 5 K, oxidation of YZ in oxygen-evolving PSII can be observed as induction of the Split S1 EPR signal from YZ• in magnetic interaction with the CaMn4 cluster, whereas oxidation of YD can be observed as the formation of the free radical EPR si

Spectral resolution of the split EPR signals induced by illumination at 5 K from the S1, S3, and S0 states in photosystem II

S-State-dependent split EPR signals that are induced by illumination at cryogenic temperatures (5 K) have been measured in spinach photosystem II without interference from the YD• radical in the g ∼ 2 region. This allows us to present the first decay-associated spectra for the split signals, which originate from the CaMn4 cluster in magnetic interaction with a nearby radical, presumably YZ•. The t

Lavar på Fridö, Södermanland, del 2

En artlista inkluderande de arter som noterades vid en exkursion till Fridö i Södermanland 2018 presenterades tidigare i Lavbulletinen. Några arter var då ännu inte bestämda eller bara preliminärt bestämda. Här kompletteras artlistan med Bacidina egenula (ny för Södermanland) och Rinodina calcarea (första fyndet utanför Öland och Gotland) vilken nu är konfirmerad genom DNA-analys.

Split EPR signals from photosystem II are modified by methanol, reflecting S state-dependent binding and alterations in the magnetic coupling in the CaMn4 cluster

Methanol binds to the CaMn4 cluster in photosystem II (PSII). Here we report the methanol dependence of the split EPR signals originating from the magnetic interaction between the CaMn4 cluster and the Y Z· radical in PSII which are induced by illumination at 5 K. We found that the magnitudes of the "split S1" and "split S3" signals induced in the S1 and S 3 states of PSII centers, respectively, a

The Streets are Talking to Me : Affective Fragments in Sisi’s Egypt

This sophisticated book presents new theoretical and analytical insights into the momentous events in the Arab world that began in 2011 and, more importantly, into life and politics in the aftermath of these events. Focusing on the qualities of the sensory world, Maria Frederika Malmström explores the dramatic differences after the Egyptian revolution and their implications for society—the lack of

New biharmonic functions on the compact Lie groups SO(n), SU(n), Sp(n)

We develop a new scheme for the construction of explicit complex-valued proper biharmonic functions on Riemannian Lie groups. We exploit this and manufacture many infinite series of uncountable families of new solutions on the special unitary group SU(n). We then show that the special orthogonal group SO(n) and the quaternionic unitary group Sp(n) fall into the scheme. As a by-product we obtain ne

Concentration of citrus fruit juices in membrane pouches with solar energy Part 1 : How solar drying setup and juice pretreatment determine the drying flux

The aim of this study was to investigate how solar drying setup and choice of juice pretreatment determine the drying flux in a fruit juice concentration process called solar assisted pervaporation. With this process, hygienic membrane pouches and solar energy are used to concentrate and preserve fruit juices. In this study, the feasibility of concentrating citrus (tangerine) juice into marmalade

Impact of AgNPs on seed germination and seedling growth : A focus study on its antibacterial potential against clavibacter michiganensis subsp. Michiganensis infection in solanum lycopersicum

This study investigated the effect of biogenic AgNPs on seed germination and seedling growth of Solanum lycopersicum. Treatment with silver nanoparticles (AgNPs) showed a significantly high germination rate and seedling growth compared to untreated seeds. Furthermore, its bactericidal effect against bacterial pathogen Clavibacter michiganensis subsp. michiganensis (cmm) infection in Solanum lycope

The role of place in city centre retailing

City centre offerings, including shopping, restaurants and cafés, and a lively atmosphere are vital place attributes, which together with several other elements create an attractive place. However, city centre retailing is facing serious competition from e-commerce and external shopping malls, and dying city centres appear to have become a worldwide epidemic in the last decade. To retain visitors

Fundamental Frequency in Feedback Words in Swedish

An investigation of the fundamental frequency in Swedish feedback words is presented. It is hypothesised that the F0-pattern differs between words signalling positive and negative feedback-i.e. agreement and disagreement with the utterance of the preceding speaker. When imitating the contrast, the negative feedback word nej 'no' is often produced with a falling F0, stretching over a larger range,