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An investigation of steric influence on the reactivity of FeV(O)(OH) tautomers in stereospecific C-H hydroxylation

Two new tetradentate N4 ligands (LN4), LN4 = Me2,Me2PyzTACN (1-(2-(3,5-dimethyl-1H-pyrazol-1-yl)ethyl)-4,7-dimethyl-1,4,7-triazacyclononane) and Me2,MeImTACN (1-((1-methyl-1H-imidazol-1-yl)methyl)-4,7-dimethyl-1,4,7-triazacyclononane) have been synthesized and their corresponding Fe(ii) complexes [FeII(Me2,Me2PyzTACN)(CF3SO3)2], 1Pz, and [FeII(Me2,MeImTACN)(CF3SO3)2], 1Im, have been prepared and c

No title

Abstract in French« Un français transformé en suédois ». Voilà comment Alf Lombard se décrivait lui-même. Il est né à Paris, son père était français et sa mère était suédoise. Il manifestait un intérêt global pour les langues romanes, mais à part le français et l’italien, c’est surtout le roumain qui était son domaine préféré. Les articles sur le français, l’italien et le roumain dans ce volume re

Introduction to A Research Agenda for Sustainable Consumption Governance

Chapter 1, ‘Introduction to A Research Agenda for Sustainable Consumption Governance’ by Oksana Mont sets the scene for the book by discussing sustainable consumption as a grand challenge. It identifies unsustainable consumption and production patterns and levels as one of the main contributing factors to the grand sustainability challenges. Reasons for failure to address unsustainable consumption

Impaired immune function accompanies social evolution in spiders

An efficient immune system is essential to the survival of many animals. Sociality increases risk of pathogen transmission, which should select for enhanced immune function. However, two hypotheses instead predict a weakened immune function: relaxed selection caused by social immunity/protection, and reduced efficacy of selection due to inbreeding, reproductive skew and female bias in social speci

Experiment

Experimentella metoder har blivit alltmer populära inom en rad olika samhällsvetenskapliga ämnen under de senaste åren. I den här boken får du lära dig vad ett experiment är, när ett experiment passar, och hur du designar och genomför experiment. Dessutom berättar författarna om experimentets historia i samhällsvetenskapen, kritik mot experiment som metod, etiska aspekter och något om framtidsutsi

Safety and efficacy of tenecteplase in patients with wake-up stroke assessed by non-contrast CT (TWIST): a multicentre, open-label, randomised controlled trial

Background: Current evidence supports the use of intravenous thrombolysis with alteplase in patients with wake-up stroke selected with MRI or perfusion imaging and is recommended in clinical guidelines. However, access to advanced imaging techniques is often scarce. We aimed to determine whether thrombolytic treatment with intravenous tenecteplase given within 4·5 h of awakening improves functiona

Structural changes in Ti1-xAlxN coatings during turning : A XANES and EXAFS study of worn tools

Structural changes in Ti1-xAlxN coated tool inserts used for turning in 316L stainless steel were investigated by XANES, EXAFS, EDS, and STEM. For coarse-grained fcc-structured Ti1-xAlxN coatings, with 0 ≤ x ≤ 0.62, the XANES spectrum changes with Al-content. XANES Ti 1s line-scans across the rake face of the worn samples reveals that TiN-enriched domains have formed during turning in Ti0.47Al0.53

Bowel control, bladder function, and quality of life in children with cloacal malformations

Introduction: Long-term outcomes of cloacal malformations remain unclear. We evaluated postoperative bowel control, bladder function and quality of life in patients under 18 years of age with cloaca. Materials and methods: This was a multi-center cross-sectional observational study accomplished by the Nordic Pediatric Surgery Research Consortium. Patients with a cloacal malformation, 4–17 years of

Occurrence of comorbidity following osteoarthritis diagnosis : a cohort study in the Netherlands

Objective: To determine the risk of comorbidity following diagnosis of knee or hip osteoarthritis (OA). Design: A cohort study was conducted using the Integrated Primary Care Information database, containing electronic health records of 2.5 million patients from the Netherlands. Adults at risk for OA were included. Diagnosis of knee or hip OA (=exposure) and 58 long-term comorbidities (=outcome) w

Bolagsstämman : Ritualer, kultur, normer och språk

På aktiebolags bolagsstämmor fastställs föregående räkenskapsårs resultat- och balansräkningar. Bolagsledningar frågas ut och granskas av aktieägarna och hålls ansvariga för sina handlingar. Styrelseledamöter, revisorer och valberedningar väljs, och beslut fattas om vinstutdelningar. Men bolagsstämmor är så mycket mer. De är fulla av symboler och känslor som kan lära oss något om den finansiella e

Attestations from Lydia, database of the project ERC Advanced Grant MAP 741182 : Mapping Ancient Polytheisms

Contribution to the online database of the project ERC Advanced Grant MAP 741182: Mapping Ancient Polytheisms.My work as a guest researcher for the MAP project focuses on the divine landscape of Hellenistic and Roman Lydia. Having collected and analysed the Anatolian testimonies to divine epithets derived from anthroponyms for the workshop My name is your name. Anthroponyms as divine attributes (2

Controlled synthesis of highly stable lead-free bismuth halide perovskite nanocrystals : tructures and photophysics

Recently, cesium bismuth halide perovskites have emerged as potential substitutes to their counterparts, cesium lead halide perovskites, owing to their low toxicity. However, the photophysics of cesium-bismuth halides nanocrystals (NCs) have not yet been fully rationalized because their structures remain highly debated. The ultraviolet-visible (UV-vis) absorption along with other photophysical pro

Large-Scale Metabolomics and the Incidence of Cardiovascular Disease

BACKGROUND: The study aimed to show the relationship between a large number of circulating metabolites and subsequent cardiovascular disease (CVD) and subclinical markers of CVD in the general population. METHODS AND RESULTS: In 2278 individuals free from CVD in the EpiHealth study (aged 45–75 years, mean age 61 years, 50% women), 790 annotated nonxenobiotic metabolites were measured by mass spect